ICCAS OpenIR
Synthesis, spectroscopic characterization and crystal structure of complex {(n-Bu)(2)Sn[(eta(5)-C5H5)Fe(eta(5)-C5H4)COO](2)}(2)
Lu, WG; Tao, JX; Ma, ZS; Xiong, M; Wang, YZ
2003-02-01
Source PublicationCHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN1001-4861
Volume19Issue:2Pages:159-163
AbstractThe novel complex {(n-Bu)(2)Sn[(eta(5)-C5H5) Fe(eta(5)-C5H4)COO](2)}(2) has been synthesized and characterized by elemental analysis, IR and NMR(H-1, C-13 and Sn-119) spectroscopy. The crystal structure of the title complex has been determined by single crystal X-ray diffraction techniques. The crystal belongs to monoclinic with space group P2(1)/c. The cell parameters are: a = 11. 753(4)Angstrom, b = 21. 133(7)Angstrom, c = 23. 374(9)Angstrom, beta = 101. 62(3)degrees, V = 5687(4)Angstrom(3), Z = 4, D-c = 1. 614Mg (.) m(-3), mu(MoKalpha) = 1. 912mm(-1), F(OOO) = 2800. The structure was refined to final R-1 = 0.0827, w R-2 = 0. 2085. The title complex molecule structure has binuclear centrosymmetric dimeric structure in which features a planar Sn2O2 core. In the structure the tin atoms rendered seven-coordination in a distorted pent agonal bipyramidal structure. The oxygen atoms O1, O2, O3, O4, O3A formed the equatorial plane and C23-Sn1-C27 is the axis of the title complex. CCDC: 193108.
KeywordDiorganotin Carboxylate Ferrocene Derivative Spectroscopic Characterization Crystal Structure
Indexed BySCI
Language英语
WOS IDWOS:000180653400010
PublisherCHINESE CHEMICAL SOCIETY
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80254
Collection中国科学院化学研究所
Corresponding AuthorTao, JX
Affiliation1.Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China
2.Shaoguan Univ, Dept Chem, Shaoguan 512005, Peoples R China
3.China Univ Geosci, Beijing 100083, Peoples R China
4.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Lu, WG,Tao, JX,Ma, ZS,et al. Synthesis, spectroscopic characterization and crystal structure of complex {(n-Bu)(2)Sn[(eta(5)-C5H5)Fe(eta(5)-C5H4)COO](2)}(2)[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2003,19(2):159-163.
APA Lu, WG,Tao, JX,Ma, ZS,Xiong, M,&Wang, YZ.(2003).Synthesis, spectroscopic characterization and crystal structure of complex {(n-Bu)(2)Sn[(eta(5)-C5H5)Fe(eta(5)-C5H4)COO](2)}(2).CHINESE JOURNAL OF INORGANIC CHEMISTRY,19(2),159-163.
MLA Lu, WG,et al."Synthesis, spectroscopic characterization and crystal structure of complex {(n-Bu)(2)Sn[(eta(5)-C5H5)Fe(eta(5)-C5H4)COO](2)}(2)".CHINESE JOURNAL OF INORGANIC CHEMISTRY 19.2(2003):159-163.
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