ICCAS OpenIR
Studies on optically active poly(menthyl methacrylate) by anionic, GTP and radical polymerization
Xu, YA; Xue, H; Zhang, SB; Gao, LX; Ding, MX
2003-04-01
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
Volume24Issue:4Pages:748-750
AbstractThe optically active polymers of ( -) -menthyl methacrylate were obtained by anionic, group transfer polymerization (GTP) and radical polymerization methods. The influences of different polymerization methods on specific rotation, yield and stereoregularity of polymers were studied. In the fluorene lithium and, (S, S)-(+)-2, 3-dimethoxy-1, 4-bis (dimethylamino) butane [(+)-DDB] complex initiative system, the specific rotation values rise slightly with the increase of molecular weight. There is no obvious difference in the specific rotation values of PMnMAs obtained by different, polymerization methods, but there is an obvious variation in stereoregularity of the polymers. And the change of the optical activity of PMn-MA is slight as compared with the variation of the stereoregularity. The tacticity of polymers is mainly syndiotactic.
KeywordOptically Active Polymer Menthyl Methacrylate Anionic Polymerization Group Transfer Polymerization Radical Polymerization
Indexed BySCI
Language英语
WOS IDWOS:000182512000047
PublisherHIGHER EDUCATION PRESS
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80224
Collection中国科学院化学研究所
Corresponding AuthorDing, MX
AffiliationChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Xu, YA,Xue, H,Zhang, SB,et al. Studies on optically active poly(menthyl methacrylate) by anionic, GTP and radical polymerization[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,24(4):748-750.
APA Xu, YA,Xue, H,Zhang, SB,Gao, LX,&Ding, MX.(2003).Studies on optically active poly(menthyl methacrylate) by anionic, GTP and radical polymerization.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,24(4),748-750.
MLA Xu, YA,et al."Studies on optically active poly(menthyl methacrylate) by anionic, GTP and radical polymerization".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 24.4(2003):748-750.
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