ICCAS OpenIR
A new C-60 dyad with intramolecular charge-transfer interaction
Liu, DF; Li, JX; Pan, HL; Li, Y; Guo, ZX; Zhu, DB
2003-04-04
Source PublicationSYNTHETIC METALS
ISSN0379-6779
Volume135Issue:1-3Pages:851-852
AbstractA new dyad based on C-60 and N,N-dimethylaniline donor was synthesized and characterized by NMR and MALDI-TOF methods. UV-Vis spectra and fluorescence spectra of the dyad were measured to study the intramolecular charge-transfer interaction. After the addition of one drop of trifluoroacetic acid (TFA) to the toluene solution of the dyad, the UV-Vis spectrum showed hyperchromic shift, and the fluorescence spectrum showed hypochromic shift, respectively. This reveals that there are intramolecular charge-transfer interaction from N,N-dimethylaniline moiety, to C-60 in both ground and excited state.
KeywordFullerenes And Derivatives Uv-vis-nir Absorption Photoluminescence
DOI10.1016/S0379-6779(02)00933-5
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000182533700400
PublisherELSEVIER SCIENCE SA
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80198
Collection中国科学院化学研究所
Corresponding AuthorGuo, ZX
Affiliation1.Chinese Acad Sci, Inst Chem, OSL, Beijing 100080, Peoples R China
2.Hebei Normal Univ, Dept Chem, Shijiazhuang, Peoples R China
Recommended Citation
GB/T 7714
Liu, DF,Li, JX,Pan, HL,et al. A new C-60 dyad with intramolecular charge-transfer interaction[J]. SYNTHETIC METALS,2003,135(1-3):851-852.
APA Liu, DF,Li, JX,Pan, HL,Li, Y,Guo, ZX,&Zhu, DB.(2003).A new C-60 dyad with intramolecular charge-transfer interaction.SYNTHETIC METALS,135(1-3),851-852.
MLA Liu, DF,et al."A new C-60 dyad with intramolecular charge-transfer interaction".SYNTHETIC METALS 135.1-3(2003):851-852.
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