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Synthesis and crystal structure of [cis-1,10-phenanthroline-palladium(II)(THF)(2)]dinitrate (THF = tetrahydrofuran)
Huang, H; Yu, SY
2003
Source PublicationCHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN0254-5861
Volume22Issue:5Pages:547-549
AbstractA mononuclear complex, cis-1,10-phenanthroline-palladium(II)(THF)(2)]dinitrate (THF = tetrahydrofuran) [Pd(C10H8N2)(C4H8O)(2)](NO3)(2) 1, has been prepared and structurally characterized by single-crystal X-ray diffraction. The crystal belongs to monoclinic system, space group P2(1)/c with a = 7.881(1), b = 27.371(3), c = 10.178(1) Angstrom, beta = 103.313(3)degrees, V 2136.5(4) Angstrom(3), M-r = 554.83, D-c = 1.725 g/cm(3), Z = 4, F(000) = 1128 and mu(MoKalpha) = 0.926 mm(-1). The structure was refined to R = 0.0678 and wR = 0.1651 for 1687 observed reflections with I > 2sigma(I). It is revealed that the central Pd(II) ion in the title complex is bonded to two THF and two phenanthroline molecules in a cis-configuration to form the coordination geometry, deviating slightly from the square plane.
KeywordCrystal Structure Pd(Ii) Complex 1 10-phenanthroline
Indexed BySCI
Language英语
WOS IDWOS:000185840000010
PublisherCHINESE JOURNAL STRUCTURAL CHEMISTRY
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80196
Collection中国科学院化学研究所
Corresponding AuthorYu, SY
AffiliationChinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Huang, H,Yu, SY. Synthesis and crystal structure of [cis-1,10-phenanthroline-palladium(II)(THF)(2)]dinitrate (THF = tetrahydrofuran)[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2003,22(5):547-549.
APA Huang, H,&Yu, SY.(2003).Synthesis and crystal structure of [cis-1,10-phenanthroline-palladium(II)(THF)(2)]dinitrate (THF = tetrahydrofuran).CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,22(5),547-549.
MLA Huang, H,et al."Synthesis and crystal structure of [cis-1,10-phenanthroline-palladium(II)(THF)(2)]dinitrate (THF = tetrahydrofuran)".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 22.5(2003):547-549.
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