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A new one-dimensional coordination polymer containing a mu-[N(CN)(2)](-) bridging ligand. Synthesis, crystal structure and magnetic properties of Mn[N(CN)(2)](2)(2,4 '-bpy)(2)(2,4 '-bpy=2,4 '-bipyridine)
Liu, CM; Zhang, DQ; Zhu, DB; Jin, XL
2003-04-01
Source PublicationTRANSITION METAL CHEMISTRY
ISSN0340-4285
Volume28Issue:3Pages:336-338
AbstractThe new one-dimensional (1D) coordination complex Mn[N(CN)(2)](2)(2,4'-bpy)(2) (1) (2,4'-bpy = 2,4'-bipyridine) has been synthesized. X-ray crystallography analysis reveals that the structure of ( 1) consists of linear chains of manganese atoms bridged by end-to-end dicyanamide ligands and coordinated by 2,4'-bipyridine ligands. Weak pi-pi interactions between pyridine planes of adjacent chains force 1D Mn[N(CN)(2)](2)(2,4'-bpy)(2) chains into interesting 2D supramolecular arrays. Variable temperature magnetic susceptibility measurement for complex (1) shows that antiferromagnetic exchange interactions exist between manganese(II) centres of the linear chain.
Indexed BySCI
Language英语
WOS IDWOS:000181852300019
PublisherKLUWER ACADEMIC PUBL
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80106
Collection中国科学院化学研究所
Corresponding AuthorZhang, DQ
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
2.Peking Univ, Inst Phys Chem, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Liu, CM,Zhang, DQ,Zhu, DB,et al. A new one-dimensional coordination polymer containing a mu-[N(CN)(2)](-) bridging ligand. Synthesis, crystal structure and magnetic properties of Mn[N(CN)(2)](2)(2,4 '-bpy)(2)(2,4 '-bpy=2,4 '-bipyridine)[J]. TRANSITION METAL CHEMISTRY,2003,28(3):336-338.
APA Liu, CM,Zhang, DQ,Zhu, DB,&Jin, XL.(2003).A new one-dimensional coordination polymer containing a mu-[N(CN)(2)](-) bridging ligand. Synthesis, crystal structure and magnetic properties of Mn[N(CN)(2)](2)(2,4 '-bpy)(2)(2,4 '-bpy=2,4 '-bipyridine).TRANSITION METAL CHEMISTRY,28(3),336-338.
MLA Liu, CM,et al."A new one-dimensional coordination polymer containing a mu-[N(CN)(2)](-) bridging ligand. Synthesis, crystal structure and magnetic properties of Mn[N(CN)(2)](2)(2,4 '-bpy)(2)(2,4 '-bpy=2,4 '-bipyridine)".TRANSITION METAL CHEMISTRY 28.3(2003):336-338.
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