ICCAS OpenIR
A novel mixed-valence Cu-I/Cu-II coordination polymer: Solvothermal synthesis, crystal structure, and magnetic properties of (CuCuII)-Cu-I(2-pyrazinecarboxylate)(2)(H2O)(ClO4)
Liu, CM; Zhang, DQ; Luo, JL; Wang, NL; Hu, HM; Zhu, DB
2003-10-06
Source PublicationEUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN1434-1948
Issue19Pages:3618-3622
AbstractThe solvothermal reaction between Cu(ClO4)(2).6H(2)O and 2-pyrazinecarboxylic acid in methanol yields a novel mixedvalence Cu-I/Cu-II coordination polymer, (CuCuII)-Cu-I(2-pyrazine-carboxylate)(2)(H2O)(ClO4) (1), in which a three-dimensional supramolecular array with square channels (9.3 x 9.3 Angstrom) is formed through crisscross arrangement of the one-dimensional (CuCuII)-Cu-I(2-pyrazinecarboxylate)(2)(H2O)(+) coordination polymer cation chains in the adjacent layers. Complex 1 exhibits weak ferromagnetic interactions. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
KeywordCopper Magnetic Properties n Ligands Solvothermal Synthesis
DOI10.1002/cjic.200300227
Indexed BySCI
Language英语
WOS IDWOS:000186050300014
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:34[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79958
Collection中国科学院化学研究所
Corresponding AuthorLiu, CM
Affiliation1.Chinese Acad Sci, Organ Solids Lab, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liu, CM,Zhang, DQ,Luo, JL,et al. A novel mixed-valence Cu-I/Cu-II coordination polymer: Solvothermal synthesis, crystal structure, and magnetic properties of (CuCuII)-Cu-I(2-pyrazinecarboxylate)(2)(H2O)(ClO4)[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2003(19):3618-3622.
APA Liu, CM,Zhang, DQ,Luo, JL,Wang, NL,Hu, HM,&Zhu, DB.(2003).A novel mixed-valence Cu-I/Cu-II coordination polymer: Solvothermal synthesis, crystal structure, and magnetic properties of (CuCuII)-Cu-I(2-pyrazinecarboxylate)(2)(H2O)(ClO4).EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(19),3618-3622.
MLA Liu, CM,et al."A novel mixed-valence Cu-I/Cu-II coordination polymer: Solvothermal synthesis, crystal structure, and magnetic properties of (CuCuII)-Cu-I(2-pyrazinecarboxylate)(2)(H2O)(ClO4)".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .19(2003):3618-3622.
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