ICCAS OpenIR
Enclathrating benzene in a neutral dicopper(II) coordination framework
Liu, HB; Yu, SY; Huang, H; Zhang, ZX
2003
Source PublicationAUSTRALIAN JOURNAL OF CHEMISTRY
ISSN0004-9425
Volume56Issue:7Pages:671-674
AbstractTwo infinite complexes {[Cu-2(O2CCH3)(4)](3-tpt)(CH3OH)(2)}(infinity) (1) and {[Cu-2(O2CPh)(4)](3-tpt)(C6H6)(1.5)}(infinity) (2) were obtained by reactions of 2,4,6-tris(3'-pyridyl)-1,3,5-triazine (3-tpt) with Cu-2(O2CCH3)(4) and Cu-2(O2CPh)(4), respectively, which have been structurally established by single-crystal X-ray diffraction. Complex (1) consists of one-dimensional zig-zag chains in its solid state, which can encapsulate methanol molecules; complex (2) consists of one-dimensional helical chains in its solid state, providing large channels which can selectively enclathrate benzene molecules. (1) crystallizes in the monoclinic space group P2(1)/c with a 8.2892(4), b 22.8479(8), c 16.9258(10) Angstrom, beta 99.1480(10)degrees, V 3164.8(3) Angstrom(3), and Z 4; (2) crystallizes in the triclinic space group P (1) over bar with a 10.7641(8), b 12.0908(8), c 18.9039(12) Angstrom, alpha 82.514(3)degrees, alpha 85.268(2)degrees, gamma 79.746(4)degrees, V 2395.9(3) Angstrom(3), and Z 2. The inclusion selectivity toward aromatic molecules was discussed.
DOI10.1071/CH03005
Indexed BySCI
Language英语
WOS IDWOS:000183804400005
PublisherC S I R O PUBLISHING
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79870
Collection中国科学院化学研究所
Corresponding AuthorYu, SY
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liu, HB,Yu, SY,Huang, H,et al. Enclathrating benzene in a neutral dicopper(II) coordination framework[J]. AUSTRALIAN JOURNAL OF CHEMISTRY,2003,56(7):671-674.
APA Liu, HB,Yu, SY,Huang, H,&Zhang, ZX.(2003).Enclathrating benzene in a neutral dicopper(II) coordination framework.AUSTRALIAN JOURNAL OF CHEMISTRY,56(7),671-674.
MLA Liu, HB,et al."Enclathrating benzene in a neutral dicopper(II) coordination framework".AUSTRALIAN JOURNAL OF CHEMISTRY 56.7(2003):671-674.
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