ICCAS OpenIR
Polyketone from ethylene with carbon monoxide catalyzed by novel catalyst systems based on copper with bidentate phosphorus chelating ligands
Huang, J; Li, FB; Zou, J; Yuan, GQ; Shi, XL; Yu, DS
2003-07-01
Source PublicationCHINESE JOURNAL OF POLYMER SCIENCE
ISSN0256-7679
Volume21Issue:4Pages:479-481
AbstractCopolymerization of ethylene with carbon monoxide was performed with Cu catalyst systems. Novel catalyst systems based on Cu (Cu(CH3COO)(2)/ligand/acid) were firstly reported for the copolymerization of ethylene with carbon monoxide, in which the ligand was a bidentate phosphorus chelating ligand. The experimental results showed that this kind of Cu catalyst system exhibited high activity. When DPPP (1,3-bis(diphenylphosphine)propane) and CH3COOH were used as ligand and acid, the corresponding catalyst system had the best activity of 108.1 g copolymer/(gCu . h). The novel Cu catalyst system had the advantages of high stability and low cost.
KeywordCopper Catalyst Copolymerization Ethylene Carbon Monoxide Polyketone
Indexed BySCI
Language英语
WOS IDWOS:000184579600014
PublisherSPRINGER
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79842
Collection中国科学院化学研究所
Corresponding AuthorYuan, GQ
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
2.Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing 100029, Peoples R China
Recommended Citation
GB/T 7714
Huang, J,Li, FB,Zou, J,et al. Polyketone from ethylene with carbon monoxide catalyzed by novel catalyst systems based on copper with bidentate phosphorus chelating ligands[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2003,21(4):479-481.
APA Huang, J,Li, FB,Zou, J,Yuan, GQ,Shi, XL,&Yu, DS.(2003).Polyketone from ethylene with carbon monoxide catalyzed by novel catalyst systems based on copper with bidentate phosphorus chelating ligands.CHINESE JOURNAL OF POLYMER SCIENCE,21(4),479-481.
MLA Huang, J,et al."Polyketone from ethylene with carbon monoxide catalyzed by novel catalyst systems based on copper with bidentate phosphorus chelating ligands".CHINESE JOURNAL OF POLYMER SCIENCE 21.4(2003):479-481.
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