ICCAS OpenIR
Silica-based hybrid nonlinear optical chromophore-trapping film prepared by sol-gel polymerization
Ji, SX; Li, Z; Zhou, XS; Cao, M; Dai, DR; Zhang, RB; Li, SJ; Ye, C
2003-03-01
Source PublicationPOLYMERS FOR ADVANCED TECHNOLOGIES
ISSN1042-7147
Volume14Issue:3-5Pages:254-259
AbstractA new thermal-resistant second-order nonlinear optical film has been prepared by in situ poling and sol-gel processing of 1,4-phenylene bis(4-trimethoxylsilylethylbenzoate) (PMSE) and Disperse Red 1 (DR1). The monomer, PMSE, was synthesized by Pt-catalyzed hydrosilylation reaction followed by alcoholysis reaction. The chromophore DR1 was embedded in the crosslinked organosilicon polymeric matrix. The film was characterized by FTIR, differential scanning calorimeter (DSC), and X-ray diffraction (XRD). The elemental analysis shows the DR1 content of the poled film to be about 11 wt%. The second-order harmonic generation (SHG) coefficient (d(33)) of the film is 16.7 pm/v and its thermal stability studies demonstrate that the onset of d(33) decay is about 130 degreesC. Copyright (C) 2003 John Wiley Sons, Ltd.
KeywordSecond-order Nonlinear Optical Film Sol-gel Process Organosilicon Polymer
DOI10.1002/pat.302
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000182654500014
PublisherJOHN WILEY & SONS LTD
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79766
Collection中国科学院化学研究所
Corresponding AuthorZhang, RB
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solid Lab, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Ji, SX,Li, Z,Zhou, XS,et al. Silica-based hybrid nonlinear optical chromophore-trapping film prepared by sol-gel polymerization[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2003,14(3-5):254-259.
APA Ji, SX.,Li, Z.,Zhou, XS.,Cao, M.,Dai, DR.,...&Ye, C.(2003).Silica-based hybrid nonlinear optical chromophore-trapping film prepared by sol-gel polymerization.POLYMERS FOR ADVANCED TECHNOLOGIES,14(3-5),254-259.
MLA Ji, SX,et al."Silica-based hybrid nonlinear optical chromophore-trapping film prepared by sol-gel polymerization".POLYMERS FOR ADVANCED TECHNOLOGIES 14.3-5(2003):254-259.
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