ICCAS OpenIR
The reaction of formaldehyde with chlorine atom
Dong, F; Qu, ZW; Zhang, QY; Kong, F
2003-03-28
Source PublicationCHEMICAL PHYSICS LETTERS
ISSN0009-2614
Volume371Issue:1-2Pages:29-34
AbstractThe elementary reaction of formaldehyde (H2CO) with chlorine atom has been experimentally investigated by the time-resolved infrared emission spectroscopy. The nascent products HCO and HCl (v less than or equal to 3) are observed. The major product channel has been identified as Cl + H2CO --> HCl + HCO. Theoretical calculations have revealed that the mechanism is a nearly barrierless peripheral hydrogen abstraction reaction. (C) 2003 Elsevier Science B.V. All rights reserved.
DOI10.1016/S0009-2614(03)00226-4
Indexed BySCI
Language英语
WOS IDWOS:000181788000005
PublisherELSEVIER SCIENCE BV
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79752
Collection中国科学院化学研究所
Corresponding AuthorKong, F
Affiliation1.Chinese Acad Sci, Inst Chem, Lab Mol React Dynam, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Div, Beijing 100864, Peoples R China
Recommended Citation
GB/T 7714
Dong, F,Qu, ZW,Zhang, QY,et al. The reaction of formaldehyde with chlorine atom[J]. CHEMICAL PHYSICS LETTERS,2003,371(1-2):29-34.
APA Dong, F,Qu, ZW,Zhang, QY,&Kong, F.(2003).The reaction of formaldehyde with chlorine atom.CHEMICAL PHYSICS LETTERS,371(1-2),29-34.
MLA Dong, F,et al."The reaction of formaldehyde with chlorine atom".CHEMICAL PHYSICS LETTERS 371.1-2(2003):29-34.
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