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Relationships between structures and hydrolytic stability of silazane compounds
Jiang, J; Peng, WQ; Zheng, ZM; Xu, CH; Xie, ZM
2002-06-01
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
Volume23Issue:6Pages:1189-1192
AbstractRelationships between structures of a series of silazane compounds and their hydrolytic stability were investigated by contacting silazane compounds directly with water vapor. It was indicated that steric hindrance of substituents strongly influenced hydrolytic stability of silazane compounds. Compounds with bigger substituents had better hydrolytic stability. As for cyclosilazanes, hydrolytic stability was also dependent on ring strength. However, steric hindrance played more dominant roles. Cyclosilazanes with phenyl substituents, hexaphenylcyclotrisilazane and polymeric compounds containing Si-N bond were of excellent hydrolytic stability due to high steric hindrance.
KeywordSilazane Compound Hydrolytic Stability Steric Hindrance Ring Strength
Indexed BySCI
Language英语
WOS IDWOS:000176272300054
PublisherHIGHER EDUCATION PRESS
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79610
Collection中国科学院化学研究所
Corresponding AuthorXie, ZM
AffiliationChinese Acad Sci, Ctr Mat Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Jiang, J,Peng, WQ,Zheng, ZM,et al. Relationships between structures and hydrolytic stability of silazane compounds[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,23(6):1189-1192.
APA Jiang, J,Peng, WQ,Zheng, ZM,Xu, CH,&Xie, ZM.(2002).Relationships between structures and hydrolytic stability of silazane compounds.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,23(6),1189-1192.
MLA Jiang, J,et al."Relationships between structures and hydrolytic stability of silazane compounds".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 23.6(2002):1189-1192.
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