ICCAS OpenIR
High-pressure effects on intramolecular electron transfer compounds
He, LM; Zhong, B; Li, H; Zhang, BW; Li, Y; Yang, GQ
2002-11-11
Source PublicationJOURNAL OF PHYSICS-CONDENSED MATTER
ISSN0953-8984
Volume14Issue:44Pages:10461-10466
AbstractWe explore the effect of pressure on the fluorescence spectra of the intramolecular electron transfer compound N-(1-pyrenylmethyl), N-methyl-4-methoxyaniline (Py-Am) and its model version, with poly(methyl methacrylate) blended in, at high pressure up to 7 GPa. The emission properties of Py-Am and pyrene show distinct difference with the increase of pressure. This difference indicates the strength of the charge transfer interaction resulting from the adjusting of the conformation of Py-Am with increase of pressure. The relationship between the electronic state of the molecule and pressure is discussed.
Indexed BySCI
Language英语
WOS IDWOS:000179541700014
PublisherIOP PUBLISHING LTD
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79546
Collection中国科学院化学研究所
Corresponding AuthorLi, Y
Affiliation1.Chinese Acad Sci, Inst Chem, Lab Photochem, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China
Recommended Citation
GB/T 7714
He, LM,Zhong, B,Li, H,et al. High-pressure effects on intramolecular electron transfer compounds[J]. JOURNAL OF PHYSICS-CONDENSED MATTER,2002,14(44):10461-10466.
APA He, LM,Zhong, B,Li, H,Zhang, BW,Li, Y,&Yang, GQ.(2002).High-pressure effects on intramolecular electron transfer compounds.JOURNAL OF PHYSICS-CONDENSED MATTER,14(44),10461-10466.
MLA He, LM,et al."High-pressure effects on intramolecular electron transfer compounds".JOURNAL OF PHYSICS-CONDENSED MATTER 14.44(2002):10461-10466.
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