ICCAS OpenIR
Asymmetric epoxidation of cinnamyl alcohol catalyzed by silica-supported casein-Co complex
Zhang, X; Han, B; Hua, YN; Huang, MY; Jiang, YY
2002-03-01
Source PublicationPOLYMERS FOR ADVANCED TECHNOLOGIES
ISSN1042-7147
Volume13Issue:3-4Pages:216-219
AbstractSilica-supported casein-Co complex (Si-CA-Co) was prepared from silica, casein and cobalt chloride, and found to be useful as a chiral catalyst for the asymmetric epoxidation 01 cinnamyl alcohol to (2R,3R)-(+)-3-phenylglycidol at 70degreesC and under I atmospheric oxygen pressure. When a proper content of cobalt in the Si-CA-Co complex and suitable reaction conditions were selected, the product and optical yield could be amounted to 70.6 and 92.0%, respectively, and the Si-CA-Co complex could be reused several times without any remarkable change in the optical catalytic activity. Copyright (C) 2002 John Wiley Sons, Ltd.
KeywordNatural Biopolymer Casein-co Complex Chiral Catalyst Asymmetric Epoxidation (2r 3r)-(+)-3-phenylglycidol
DOI10.1002/pat.176
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000174200300011
PublisherJOHN WILEY & SONS LTD
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79518
Collection中国科学院化学研究所
Corresponding AuthorHan, B
AffiliationChinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhang, X,Han, B,Hua, YN,et al. Asymmetric epoxidation of cinnamyl alcohol catalyzed by silica-supported casein-Co complex[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2002,13(3-4):216-219.
APA Zhang, X,Han, B,Hua, YN,Huang, MY,&Jiang, YY.(2002).Asymmetric epoxidation of cinnamyl alcohol catalyzed by silica-supported casein-Co complex.POLYMERS FOR ADVANCED TECHNOLOGIES,13(3-4),216-219.
MLA Zhang, X,et al."Asymmetric epoxidation of cinnamyl alcohol catalyzed by silica-supported casein-Co complex".POLYMERS FOR ADVANCED TECHNOLOGIES 13.3-4(2002):216-219.
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