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Synthesis and X-ray structure of dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II)
Li, ZL; Sun, WH; Wang, LY; Wu, B; He, C; Yan, CH
2002-06-01
Source PublicationJOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN1074-1542
Volume32Issue:5-6Pages:107-111
AbstractDichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II) was formed in the reaction of 8-(diphenylphosphino)quinoline with nickel chloride in air. The title complex crystallized in P1 with the following cell dimensions: a = 8.5685(3) Angstrom, b = 10.7736(2) Angstrom, c = 13.4391(5) Angstrom, and alpha = 110.447(2)degrees, beta = 94.577(2)degrees; gamma = 111.138(2)degrees, giving a volume of 1053.75(6) Angstrom(3). The trans-dichlorobis(8-(diphenylphosphinyl)quinoline) nickel(II) adapts a central symmetric distorted octahedron. The structure is compared to other nickel(II) cation complexes, and possible reasons for the bonding states are discussed.
Keyword8-(Diphenylphosphino)Quinoline X-ray Single Crystal Structure Nickel Chloride
Indexed BySCI
Language英语
WOS IDWOS:000175903400001
PublisherKLUWER ACADEMIC/PLENUM PUBL
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79324
Collection中国科学院化学研究所
Corresponding AuthorSun, WH
Affiliation1.Chinese Acad Sci, Inst Chem, State Key Lab Engn Plast, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
3.Peking Univ, Peking Univ Nonius BV Demo Lab Xray Diffract, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Li, ZL,Sun, WH,Wang, LY,et al. Synthesis and X-ray structure of dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II)[J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY,2002,32(5-6):107-111.
APA Li, ZL,Sun, WH,Wang, LY,Wu, B,He, C,&Yan, CH.(2002).Synthesis and X-ray structure of dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II).JOURNAL OF CHEMICAL CRYSTALLOGRAPHY,32(5-6),107-111.
MLA Li, ZL,et al."Synthesis and X-ray structure of dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II)".JOURNAL OF CHEMICAL CRYSTALLOGRAPHY 32.5-6(2002):107-111.
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