ICCAS OpenIR
Synthesis, crystal structure and third-order nonlinear optical behavior of a novel dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate
Liu, CM; Zhang, DQ; Song, YL; Zhan, CL; Li, YL; Zhu, DB
2002-07-01
Source PublicationEUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN1434-1948
Issue7Pages:1591-1594
AbstractThe first dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate (dmit) [Zn(dmit)(2,2'-bpy)](2) (2,2'-bpy = 2,2'-bipyridine) (1), which exhibits a good third-order nonlinear refraction effect, was synthesized by a ligand exchange reaction between [(Et4N)(2)Zn(dmit)(2)] and [Cu(2,2'-bpy)(NO3)(2)].2H(2)O. A Z-scanning measurement of complex 1 gives the third-order nonlinear refraction index n(2) = 3.72 x 10(-18) m(2)/W and the real part Rechi((3)) = 1.01 x 10(-12) esu. Crystal data for 1: monoclinic, P2(1)/c (No. 14), a = 11.556(2) Angstrom, b 9.141(2) Angstrom, c = 15.020(3) Angstrom, beta = 109.55(3)degrees, Z = 4. ((C) Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002).
KeywordZinc n Ligands s Ligands Crystal Structure Nonlinear Optics
Indexed BySCI
Language英语
WOS IDWOS:000176717700005
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:32[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79302
Collection中国科学院化学研究所
Corresponding AuthorZhang, DQ
Affiliation1.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Organ Solids Lab, Beijing 100080, Peoples R China
2.Harbin Inst Technol, Dept Appl Phys, Harbin 150001, Peoples R China
Recommended Citation
GB/T 7714
Liu, CM,Zhang, DQ,Song, YL,et al. Synthesis, crystal structure and third-order nonlinear optical behavior of a novel dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2002(7):1591-1594.
APA Liu, CM,Zhang, DQ,Song, YL,Zhan, CL,Li, YL,&Zhu, DB.(2002).Synthesis, crystal structure and third-order nonlinear optical behavior of a novel dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(7),1591-1594.
MLA Liu, CM,et al."Synthesis, crystal structure and third-order nonlinear optical behavior of a novel dimeric mixed-ligand zinc(II) complex of 1,3-dithiole-2-thione-4,5-dithiolate".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .7(2002):1591-1594.
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