ICCAS OpenIR
Synthesis and characterization of novel lanthanocene complexes with dichalcogenolate o-carboranyl ligands
Yu, XY; Jin, GX; Weng, LH
2002-11-01
Source PublicationCHINESE JOURNAL OF CHEMISTRY
ISSN1001-604X
Volume20Issue:11Pages:1256-1262
AbstractReactions of [ Cp(2)Ln(mu-Cl)](2) (Cp = eta(5)-C5H5, Ln = Nd, Yb, Dy, Gd, Er) with an equivalent of [ (THF)(3)LiE2C2B10H10Li. (TT-IF) (THF)](2) (E = S, Se) in THF afforded the dinuclear sandwich complexes of formula[Cp(2)LnE(2)C(2)B(10)H(10)](2)[Li(THF)(4)](2) [E = S, Ln = Nd (1a), Yb (2a), Dy (3a), Gd (4a), Er (5a); E = Se, Ln = Nd (1b), Yb (2b), Dy (3b), Gd (4b), Er (5b)]. The molecular structures of complexes la, 2a and 2b were determined by the single crystal X-ray structure analyses. Two lanthanide atoms are connected by a pair chalcogen (eta(1), eta(2)-E2C2B10H10) bridging ligands and the central Ln(2)E(2) four membered ring is not planar.
KeywordLanthanocene Complex Crystal Structure Dichalcogenolate O-carborane Metathesis Reaction
Indexed BySCI
Language英语
WOS IDWOS:000179210800018
PublisherSCIENCE CHINA PRESS
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79296
Collection中国科学院化学研究所
Corresponding AuthorJin, GX
Affiliation1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Fudan Univ, Dept Chem, Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
Recommended Citation
GB/T 7714
Yu, XY,Jin, GX,Weng, LH. Synthesis and characterization of novel lanthanocene complexes with dichalcogenolate o-carboranyl ligands[J]. CHINESE JOURNAL OF CHEMISTRY,2002,20(11):1256-1262.
APA Yu, XY,Jin, GX,&Weng, LH.(2002).Synthesis and characterization of novel lanthanocene complexes with dichalcogenolate o-carboranyl ligands.CHINESE JOURNAL OF CHEMISTRY,20(11),1256-1262.
MLA Yu, XY,et al."Synthesis and characterization of novel lanthanocene complexes with dichalcogenolate o-carboranyl ligands".CHINESE JOURNAL OF CHEMISTRY 20.11(2002):1256-1262.
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