ICCAS OpenIR
Reactivity ratios of free monomers and their charge-transfer complex in the copolymerization of N-butyl maleimide and styrene
Zhao, YL; Li, HM; Liu, PS; Liu, HW; Jiang, J; Xi, F
2002-04-01
Source PublicationJOURNAL OF APPLIED POLYMER SCIENCE
ISSN0021-8995
Volume83Issue:14Pages:3007-3012
AbstractAs for the charge-transfer complex (CTC) formed by N-butyl maleimide (NMBI) and styrene in chloroform, the complex formation constant was determined by H-1-NMR of Hanna-Ashbaugh. The copolymerization of NBMI (NBMI, M-1) and styrene (St, M-2) in chloroform using AIBN as an initiator was investigated. On the basis of the kinetic model proposed by Shan, the reactivity ratios of free monomers and CTC in the copolymerization were calculated to be r(12) = 0.0440, r(21) = 0.0349, r(1C) = 0.00688, r(2C) = 0.00476, and the ratios of rate constants were obtained to be k(1C)/k(12) = 6.40, k(2C)/k(21) = 7.33. In addition, the copolymer was characterized by IR, H-1-NMR, DSC, and TGA. (C) 2002 John Wiley Sons, Inc.
KeywordN-butyl Maleimide Styrene Charge-transfer Complex Solution Copolymerization Reactivity Ratios
Indexed BySCI
Language英语
WOS IDWOS:000173534600007
PublisherJOHN WILEY & SONS INC
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79284
Collection中国科学院化学研究所
Corresponding AuthorXi, F
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
2.Xiangtan Univ, Coll Chem & Chem Engn, Xiangtan 411105, Peoples R China
Recommended Citation
GB/T 7714
Zhao, YL,Li, HM,Liu, PS,et al. Reactivity ratios of free monomers and their charge-transfer complex in the copolymerization of N-butyl maleimide and styrene[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2002,83(14):3007-3012.
APA Zhao, YL,Li, HM,Liu, PS,Liu, HW,Jiang, J,&Xi, F.(2002).Reactivity ratios of free monomers and their charge-transfer complex in the copolymerization of N-butyl maleimide and styrene.JOURNAL OF APPLIED POLYMER SCIENCE,83(14),3007-3012.
MLA Zhao, YL,et al."Reactivity ratios of free monomers and their charge-transfer complex in the copolymerization of N-butyl maleimide and styrene".JOURNAL OF APPLIED POLYMER SCIENCE 83.14(2002):3007-3012.
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