ICCAS OpenIR
Hydrothermal synthesis, crystal structures and magnetic properties of two bimetallic cage cluster vanadate complexes [Co(phen)(2)](2)V4O12 and [Co(2,2 '-bipy)(2)](2)V4O12
Liu, CM; Zhang, DQ; Xiong, M; Dai, MQ; Hu, HM; Zhu, DB
2002-11-01
Source PublicationJOURNAL OF COORDINATION CHEMISTRY
ISSN0095-8972
Volume55Issue:11Pages:1327-1335
AbstractTwo new bimetallic cluster complexes, [Co(phen)(2)](2)V4O12 1 (phen = phenanthroline) and [Co(2,2'-bipy)(2)](2)V4O12 2 (2,2'-bipy = 2,2'-bipyridine), have been synthesized hydrothermally. X-ray crystallography reveals that both 1 and 2 possess a similar metal cage cluster core, Co2V4O12. Magnetic studies of I and 2 indicate that both the complexes exhibit antiferromagnetic interactions between the cobalt(II) ions.
KeywordHydrothermal Synthesis Cobalt Cluster Crystal Structure Polyoxovanadium Magnetic Properties
DOI10.1080/0095897021000036640
Indexed BySCI
Language英语
WOS IDWOS:000179164300012
PublisherTAYLOR & FRANCIS LTD
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79204
Collection中国科学院化学研究所
Corresponding AuthorZhu, DB
Affiliation1.Chinese Acad Sci, Inst Chem, Organ Solids Lab, Ctr Mol Sci, Beijing 100080, Peoples R China
2.China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China
Recommended Citation
GB/T 7714
Liu, CM,Zhang, DQ,Xiong, M,et al. Hydrothermal synthesis, crystal structures and magnetic properties of two bimetallic cage cluster vanadate complexes [Co(phen)(2)](2)V4O12 and [Co(2,2 '-bipy)(2)](2)V4O12[J]. JOURNAL OF COORDINATION CHEMISTRY,2002,55(11):1327-1335.
APA Liu, CM,Zhang, DQ,Xiong, M,Dai, MQ,Hu, HM,&Zhu, DB.(2002).Hydrothermal synthesis, crystal structures and magnetic properties of two bimetallic cage cluster vanadate complexes [Co(phen)(2)](2)V4O12 and [Co(2,2 '-bipy)(2)](2)V4O12.JOURNAL OF COORDINATION CHEMISTRY,55(11),1327-1335.
MLA Liu, CM,et al."Hydrothermal synthesis, crystal structures and magnetic properties of two bimetallic cage cluster vanadate complexes [Co(phen)(2)](2)V4O12 and [Co(2,2 '-bipy)(2)](2)V4O12".JOURNAL OF COORDINATION CHEMISTRY 55.11(2002):1327-1335.
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