ICCAS OpenIR
{Di-mu-bromotetra [N,N '-bis(3,5-dimethylanil)-4-methyl-2,6-bis(imino) phenoxy]dinickel}bromide
Han, LQ; Li, TS; Sun, WH; Wang, LY; Guo, DW; Shao, CX; Wang, HG
2002-11-01
Source PublicationTRANSITION METAL CHEMISTRY
ISSN0340-4285
Volume27Issue:8Pages:844-848
AbstractA new bis-Schiff base ligand, N,N'-bis(3,5-dimethylanil)-4-methyl-2,6-bis(imino) phenol was prepared by reacting 2,6-diformyl-4-methylphenol with 3,5-dimethylaniline. Treatment of the ligand with (DME) NiBr2 (DME=1,2-dimethoxyethane) gave the novel dinuclear bromo-bridged complex, {di-mu-bromotetra [ N,N'-bis(3,5-dimethylanil)-4-methyl-2,6-bis( imino) phenoxy] dinickel} bromide, whose crystal structure was confirmed by single crystal X-ray analysis. The calculation, via the molecular mechanics method, performs well to reproduce the crystal structure. The complex shows some activity in respect of ethene oligomerization under mild conditions with methylaluminoxane (MAO) as a co-catalyst.
Indexed BySCI
Language英语
WOS IDWOS:000179572700007
PublisherKLUWER ACADEMIC PUBL
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79200
Collection中国科学院化学研究所
Corresponding AuthorSun, WH
Affiliation1.Chinese Acad Sci, State Key Lab Engn Plast, Beijing 100080, Peoples R China
2.Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China
3.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
4.Nankai Univ, State Key Lab Funct Polymers, Tianjin 300071, Peoples R China
Recommended Citation
GB/T 7714
Han, LQ,Li, TS,Sun, WH,et al. {Di-mu-bromotetra [N,N '-bis(3,5-dimethylanil)-4-methyl-2,6-bis(imino) phenoxy]dinickel}bromide[J]. TRANSITION METAL CHEMISTRY,2002,27(8):844-848.
APA Han, LQ.,Li, TS.,Sun, WH.,Wang, LY.,Guo, DW.,...&Wang, HG.(2002).{Di-mu-bromotetra [N,N '-bis(3,5-dimethylanil)-4-methyl-2,6-bis(imino) phenoxy]dinickel}bromide.TRANSITION METAL CHEMISTRY,27(8),844-848.
MLA Han, LQ,et al."{Di-mu-bromotetra [N,N '-bis(3,5-dimethylanil)-4-methyl-2,6-bis(imino) phenoxy]dinickel}bromide".TRANSITION METAL CHEMISTRY 27.8(2002):844-848.
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