ICCAS OpenIR
In situ electrochemical STM of charge-transfer complex on Cu(111)
Xu, QM; Zhang, B; Wan, LJ; Wang, C; Bai, CL; Zhu, DB
2002-10-01
Source PublicationSURFACE SCIENCE
ISSN0039-6028
Volume517Issue:1-3Pages:52-58
AbstractAdsorption and adlayer structures of ferrite magnetic anion [Fe(C2O4)(3)](3-) organic pi-electron donor bis(ethylene-dithio) tetrathiafulvalene (bedt-ttf) and charge-transfer complex (bedt-ttf)(5)(H3O)Fe(C2O4)(3) . CH2Cl2, have been investigated by using electrochemical scanning tunneling microscopy on Cu(I 1 1) electrode surfaces in aqueous HClO4 solution. It was found that [Fe(C2O4)(3)](3-) formed a (4 x 4) structure with a characteristic propeller shape for each anion and that bedt-ttf adlayer had a (4 x 6) symmetry. For the complex, [Fe(C2O4)(3)](3-) and bedt-ttf co-adsorbed on Cu(1 1 1) surface and yielded a well-defined two-dimensional network, in which one [Fe(C2O4)(3)](3-) interacted with three bedt-ttf molecules. (C) 2002 Elsevier Science B.V. All rights reserved.
KeywordAdsorption Kinetics Electrochemical Methods Scanning Tunneling Microscopy Single Crystal Surfaces
Indexed BySCI
Language英语
WOS IDWOS:000178411400008
PublisherELSEVIER SCIENCE BV
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79048
Collection中国科学院化学研究所
Corresponding AuthorWan, LJ
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Xu, QM,Zhang, B,Wan, LJ,et al. In situ electrochemical STM of charge-transfer complex on Cu(111)[J]. SURFACE SCIENCE,2002,517(1-3):52-58.
APA Xu, QM,Zhang, B,Wan, LJ,Wang, C,Bai, CL,&Zhu, DB.(2002).In situ electrochemical STM of charge-transfer complex on Cu(111).SURFACE SCIENCE,517(1-3),52-58.
MLA Xu, QM,et al."In situ electrochemical STM of charge-transfer complex on Cu(111)".SURFACE SCIENCE 517.1-3(2002):52-58.
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