ICCAS OpenIR
Hydrothermal syntheses and crystal structures of two- dimensional (2D) layered vanadium oxide complexes: M(bipy)(H2O)V2O6 (M = Ni, Co, bipy = bipyridine) and [Ni(bipy)(2)V6O17]
Liu, CM; Gao, S; Hu, HM; Jin, XL; Kou, HZ
2002
Source PublicationJOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN1472-7773
Issue4Pages:598-601
AbstractDouble layered vanadium oxide metal coordination complexes, [Ni(bipy)(H2O)V2O6](infinity) 1 and {[Ni(bipy)(2)](2)V6O17}(infinity) 2, have been isolated from the same hydrothermal reaction container. X-Ray crystallography shows that 1 consists of unique two-dimensional layers constructed from a vanadium oxide chain {V2O6}(n)(2n-) and covalently linked by Ni(bipy)(H2O)(2+) subunits. In contrast 2 and the previously reported Zn(bipy)(2)V6O17 are isomorphic compounds. Only [Co(bipy)(H2O)V2O6](infinity), 3, was obtained when cobalt was substituted for nickel in a similar reaction, and X-ray diffraction analysis reveals that the topology of 3 is essentially identical to that of 1. The magnetic behavior of 1 and 2 suggests a dominant single ion effect with only very weak magnetic interactions.
DOI10.1039/b105700f
Indexed BySCI
Language英语
WOS IDWOS:000173818700020
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:43[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/79014
Collection中国科学院化学研究所
Corresponding AuthorGao, S
Affiliation1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
2.Chinese Acad Sci, Organ Solids Lab, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liu, CM,Gao, S,Hu, HM,et al. Hydrothermal syntheses and crystal structures of two- dimensional (2D) layered vanadium oxide complexes: M(bipy)(H2O)V2O6 (M = Ni, Co, bipy = bipyridine) and [Ni(bipy)(2)V6O17][J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS,2002(4):598-601.
APA Liu, CM,Gao, S,Hu, HM,Jin, XL,&Kou, HZ.(2002).Hydrothermal syntheses and crystal structures of two- dimensional (2D) layered vanadium oxide complexes: M(bipy)(H2O)V2O6 (M = Ni, Co, bipy = bipyridine) and [Ni(bipy)(2)V6O17].JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS(4),598-601.
MLA Liu, CM,et al."Hydrothermal syntheses and crystal structures of two- dimensional (2D) layered vanadium oxide complexes: M(bipy)(H2O)V2O6 (M = Ni, Co, bipy = bipyridine) and [Ni(bipy)(2)V6O17]".JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS .4(2002):598-601.
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