Preparation and properties of a novel nonlinear optical crystal: MnHg(SCN)(4)(H2O)(2).2(C3H6CONCH3)
Wang, XQ; Xu, D; Cheng, XF; Lu, MK; Yuan, DR; Huang, J; Lu, GW; Xie, TX; Wang, SL; Lu, GT; Zhao, JQ; Yang, ZH; Chen, Y; Zhou, YQ
AbstractIn this article, diaquatetrakis (thiocyanato) manganese(II) mercury (II)-N-methyl-2-pyrrolidone, MnHg(SCN)(4)(H2O)(2).2(C3H6CONCH3), (abbreviated as MMTWMP), a new organometallic nonlinear optical crystal material is reported. The structure, optical and thermal characterizations were determined by elemental analysis, infrared and Raman spectroscopy, X-ray powder diffraction, thermogravimetric analysis, differential scanning calorimetry, special heat, SHG measurements and UV/Vis/NIR optical transmission spectra. It belongs to the tetragonal crystallographic system, with cell parameters: a = 12.1294, c = 8.2238Angstrom, V = 1211.27Angstrom(3). Single crystals with dimensions up to 8 x 7 x 5 mm(3) have been obtained. The morphology of the crystals was indexed. The MMTWMP crystal exhibits good physicochemical stability at normal temperature and pressure. Its UV transparency cutoff is 360 run, which is shifted to the violet by 13 nm, as compared with MnHg(SCN), (MMTC), the optical transmission is 44.82% at 404 nm, which is by 17.46% higher than that of MMTC.
KeywordDcrystal Growth Mnhg(Scn)(4)(H2o)(2).2(C3h6conch3) Spectroscopic Characterizations Thermal Properties Optical Properties
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WOS IDWOS:000176200200003
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Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorWang, XQ
Affiliation1.Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
2.Shandong Univ, Inst Modern Anal, Coll Environm Sci & Engn, Jinan 250100, Peoples R China
3.Shandong Univ, Dept Phys, Jinan 250100, Peoples R China
4.Petrol Univ, Lab Geochem & Lithosphere Dynam, Dongying 250765, Peoples R China
5.Chinese Acad Sci, Inst Chem, State Key Engn Lab, Beijing 100080, Peoples R China
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Wang, XQ,Xu, D,Cheng, XF,et al. Preparation and properties of a novel nonlinear optical crystal: MnHg(SCN)(4)(H2O)(2).2(C3H6CONCH3)[J]. CRYSTAL RESEARCH AND TECHNOLOGY,2002,37(6):551-563.
APA Wang, XQ.,Xu, D.,Cheng, XF.,Lu, MK.,Yuan, DR.,...&Zhou, YQ.(2002).Preparation and properties of a novel nonlinear optical crystal: MnHg(SCN)(4)(H2O)(2).2(C3H6CONCH3).CRYSTAL RESEARCH AND TECHNOLOGY,37(6),551-563.
MLA Wang, XQ,et al."Preparation and properties of a novel nonlinear optical crystal: MnHg(SCN)(4)(H2O)(2).2(C3H6CONCH3)".CRYSTAL RESEARCH AND TECHNOLOGY 37.6(2002):551-563.
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