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Development of highly effective encapsulating surfactants for Mukaiyama aldol reactions in water
Tian, HY; Li, HJ; Chen, YJ; Wang, D; Li, CJ
2002-09-04
Source PublicationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
Volume41Issue:18Pages:4523-4527
AbstractAmphiphilic calix[6]arene derivatives 1a-b and calix[4]arene 1d-1e, as well as aliphatic (2a-b) and aromatic (2c-2d) anionic surfactants, were studied for their encapsulating ability in stabilizing water-sensitive compounds. They were found to be efficient surfactants for Sc(OTf)(3)-catalyzed Mukaiyama aldol reactions of labile enol ethers with aldehydes in water. The results indicate that a hydrophobic microenvironment was formed in the reaction system with either the amphiphilic calix[6]arene derivatives or the simple aromatic surfactants, which could encapsulate and stabilize some labile silyl enol ethers and thus promote the reactions.
DOI10.1021/ie010782k
Indexed BySCI
Language英语
WOS IDWOS:000177808700013
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78978
Collection中国科学院化学研究所
Corresponding AuthorTian, HY
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
2.Tulane Univ, Dept Chem, New Orleans, LA 70118 USA
Recommended Citation
GB/T 7714
Tian, HY,Li, HJ,Chen, YJ,et al. Development of highly effective encapsulating surfactants for Mukaiyama aldol reactions in water[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2002,41(18):4523-4527.
APA Tian, HY,Li, HJ,Chen, YJ,Wang, D,&Li, CJ.(2002).Development of highly effective encapsulating surfactants for Mukaiyama aldol reactions in water.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,41(18),4523-4527.
MLA Tian, HY,et al."Development of highly effective encapsulating surfactants for Mukaiyama aldol reactions in water".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 41.18(2002):4523-4527.
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