ICCAS OpenIR
Catalytic behavior of silica-supported methylcellulose-oxalic acid-Pt complex in asymmetric hydrogenation of 2-butanone and itaconic acid
Liu, HW; Xin, F; Wu, LM; Huang, MY; Jiang, YY
2002-03-01
Source PublicationPOLYMERS FOR ADVANCED TECHNOLOGIES
ISSN1042-7147
Volume13Issue:3-4Pages:210-215
AbstractA new silica-supported biopolymer-oxalic acid-Pt complex was prepared by a simple method. Methylcellulose (mc) reacted with oxalic acid in the presence of silica to give a complex SiO2-MC-(COOH)(2) on the surface of silica, then reacted with H2PtCl6.6H(2)O to form a Pt complex [SiO2-MC-(COOH)(2)-Pt]. This ocmplex was found to be able to catalyze the asymmetric hydrogenation of 2-butanone to (S)-(+)-2-butanol and itaconic acid to (S)-(-)-methylsuccinic, respectively, at room temperature and under 1 atm H-2. The experimental results showed that the product and optical yields were remarkable affected by the Pt content in the complex and the catalyst could be reused without any remarkable change in optical catalytic activity. Copyright (C) 2002 John Wiley Sons, Ltd.
KeywordPlatinum Complex Catalysis Oxalic Acid Asymmetric Hydrogenation 2-butanone Itaconic Acid
DOI10.1002/pat.175
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000174200300010
PublisherJOHN WILEY & SONS LTD
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78808
Collection中国科学院化学研究所
Corresponding AuthorLiu, HW
AffiliationChinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liu, HW,Xin, F,Wu, LM,et al. Catalytic behavior of silica-supported methylcellulose-oxalic acid-Pt complex in asymmetric hydrogenation of 2-butanone and itaconic acid[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2002,13(3-4):210-215.
APA Liu, HW,Xin, F,Wu, LM,Huang, MY,&Jiang, YY.(2002).Catalytic behavior of silica-supported methylcellulose-oxalic acid-Pt complex in asymmetric hydrogenation of 2-butanone and itaconic acid.POLYMERS FOR ADVANCED TECHNOLOGIES,13(3-4),210-215.
MLA Liu, HW,et al."Catalytic behavior of silica-supported methylcellulose-oxalic acid-Pt complex in asymmetric hydrogenation of 2-butanone and itaconic acid".POLYMERS FOR ADVANCED TECHNOLOGIES 13.3-4(2002):210-215.
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