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Liquid-phase hydrogenation of furfural to tetrahydrofurfuryl alcohol catalyzed by polymer resin supported palladium catalysts
Yin, JB; Chen, XS; Zhang, L; Liu, A; Yang, YN; Yin, M; Lou, L
2002-07-01
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
Volume23Issue:7Pages:1363-1366
AbstractThree kinds of polymer resin supported Pd catalysts were prepared by mixing PdCl2, with alkaline styrene anion exchange resins[D392 -NH2, D382, -NHCH3, D301R, -NH(CH3)(2)], strongly alkaline styrene anion exchanged resin [201 X 7DVB, -NH+ (CH3)(3)] and alkaline epoxy exchange resin (701, -NH2), and hydrogenating in liquid phase at 1.013 X 10(5) Pa. The hydrogenation of furfural was studied under the reaction conditions such as solvent, temperature. Pd content in the supported catalyst and the amount of the catalyst. The yield of hydrogenation reaction of furfural markedly increased to 100% and the selectivity to tetrahydrofurfuryl alcohol increased to over 98% by polymer (alkaline styrene anion exchange resins D392, -NH2, D382, -NHCH3) supported palladium catalysts comparing with the yield over 70% and selectivity over 97% by palladium catalyst, in 50% alcohol-50% water or pure water solution at 1.013 X 10(5) Pa. The relationship between hydrogenation and the structures of functional group in the supporting resin was examined by XPS method.
KeywordPalladium Polymer Supported Catalyst Furfural Hydrogenation
Indexed BySCI
Language英语
WOS IDWOS:000176908400036
PublisherHIGHER EDUCATION PRESS
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78798
Collection中国科学院化学研究所
Corresponding AuthorYin, JB
Affiliation1.Jilin Inst Technol, Dept Chem Engn, Seoul 130012, South Korea
2.Chinese Acad Sci, Changchun Inst Appl Chem, China Petr Corp, Changchun 130022, Peoples R China
3.Chinese Acad Sci, Union Lab Polymer Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Yin, JB,Chen, XS,Zhang, L,et al. Liquid-phase hydrogenation of furfural to tetrahydrofurfuryl alcohol catalyzed by polymer resin supported palladium catalysts[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,23(7):1363-1366.
APA Yin, JB.,Chen, XS.,Zhang, L.,Liu, A.,Yang, YN.,...&Lou, L.(2002).Liquid-phase hydrogenation of furfural to tetrahydrofurfuryl alcohol catalyzed by polymer resin supported palladium catalysts.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,23(7),1363-1366.
MLA Yin, JB,et al."Liquid-phase hydrogenation of furfural to tetrahydrofurfuryl alcohol catalyzed by polymer resin supported palladium catalysts".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 23.7(2002):1363-1366.
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