ICCAS OpenIR
Chloro-nickel and chloro-cobalt complexes containing phosphine ligands: efficient initiators for polymerization of alkynes
Zhan, XW; Xu, SG; Yang, MJ; Lei, ZQ
2002
Source PublicationCATALYSIS LETTERS
ISSN1011-372X
Volume80Issue:1-2Pages:59-61
AbstractWe have developed a new series of single-component air- and moisture-stable catalysts for alkyne polymerization based on chloro-nickel and chloro-cobalt complexes containing phosphine ligands. The polymerization of p-diethynylbenzene initiated by these complexes proceeds smoothly in the presence of amines at room temperature to afford soluble pi-conjugated polymers in yields as high as 81% with weight-average molecular weight up to 17 600.
KeywordTransition Metal Chloride Catalyst Alkyne Polymerization
Indexed BySCI
Language英语
WOS IDWOS:000176801500010
PublisherKLUWER ACADEMIC/PLENUM PUBL
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78682
Collection中国科学院化学研究所
Corresponding AuthorZhan, XW
Affiliation1.Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhan, XW,Xu, SG,Yang, MJ,et al. Chloro-nickel and chloro-cobalt complexes containing phosphine ligands: efficient initiators for polymerization of alkynes[J]. CATALYSIS LETTERS,2002,80(1-2):59-61.
APA Zhan, XW,Xu, SG,Yang, MJ,&Lei, ZQ.(2002).Chloro-nickel and chloro-cobalt complexes containing phosphine ligands: efficient initiators for polymerization of alkynes.CATALYSIS LETTERS,80(1-2),59-61.
MLA Zhan, XW,et al."Chloro-nickel and chloro-cobalt complexes containing phosphine ligands: efficient initiators for polymerization of alkynes".CATALYSIS LETTERS 80.1-2(2002):59-61.
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