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Cobalt and nickel complexes bearing 2,6-bis (imino) phenoxy ligands: syntheses, structures and oligomerization studies
Wang, LY; Sun, WH; Han, LQ; Li, ZL; Hu, YL; He, C; Yan, CH
2002-05-01
Source PublicationJOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN0022-328X
Volume650Issue:1-2Pages:59-64
AbstractA series of new cobalt and nickel complexes LMX2 (M = Co, X = Cl; M = Ni, X = Br) bearing 2, 6-bis(imino)phenoxy ligands were synthesized. The solid-state structures of 1 and 4 have been determined by single-crystal X-ray diffraction study. Treatment of the complexes LMX2 with methylaluminoxane (MAO) leads to active catalysts for oligornerization of ethylene with catalytic activities in the range of 1.2 x 10(5)-2.1 x 10(5) g mol(-1) h(-1) atm(-1) for Ni complexes, and similar to10(3) g mol(-1) h(-1) atm(-1) for Co complexes. The oligomers were olefins from C-4 to C-16. (C) 2002 Published by Elsevier Science B.V.
KeywordCobalt Nickel Ethylene Oligomerization Crystal Structures
Indexed ByIC ; CCR ; SCI
Language英语
WOS IDWOS:000175893500006
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:75[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78672
Collection中国科学院化学研究所
Corresponding AuthorSun, WH
Affiliation1.Chinese Acad Sci, State Key Lab Engn Plast, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China
3.Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Nonius BV Demo Lab Xray Diffract, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Wang, LY,Sun, WH,Han, LQ,et al. Cobalt and nickel complexes bearing 2,6-bis (imino) phenoxy ligands: syntheses, structures and oligomerization studies[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2002,650(1-2):59-64.
APA Wang, LY.,Sun, WH.,Han, LQ.,Li, ZL.,Hu, YL.,...&Yan, CH.(2002).Cobalt and nickel complexes bearing 2,6-bis (imino) phenoxy ligands: syntheses, structures and oligomerization studies.JOURNAL OF ORGANOMETALLIC CHEMISTRY,650(1-2),59-64.
MLA Wang, LY,et al."Cobalt and nickel complexes bearing 2,6-bis (imino) phenoxy ligands: syntheses, structures and oligomerization studies".JOURNAL OF ORGANOMETALLIC CHEMISTRY 650.1-2(2002):59-64.
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