ICCAS OpenIR
Reaction of CH with NO2 studied by time-resolved FTIR spectroscopy
Ren, L; Kong, F
2002-10-17
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY A
ISSN1089-5639
Volume106Issue:41Pages:9499-9501
AbstractThe gaseous reaction of CH + NO2 has been investigated by using time-resolved FTIR spectroscopy. The CH radical was generated by the laser photolysis of CHBr3 at 248 nm. All of the reaction products, NO, CO, HNO (v(1)), CO2 (v(3)) and OH, in their vibrationally excited states were observed. The reaction leading to CO + HNO is identified as the most favorable channel. Producing HCO + NO is a minor reaction channel. A much less competitive channel leading to OH + CNO may also occur. The observed CO2 species may come from the secondary reaction HCO + NO2. The observation agrees with the recent theoretical prediction based on ab initio calculations.
DOI10.1021/jp0204408
Indexed BySCI
Language英语
WOS IDWOS:000178548500018
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78582
Collection中国科学院化学研究所
Corresponding AuthorKong, F
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Ren, L,Kong, F. Reaction of CH with NO2 studied by time-resolved FTIR spectroscopy[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2002,106(41):9499-9501.
APA Ren, L,&Kong, F.(2002).Reaction of CH with NO2 studied by time-resolved FTIR spectroscopy.JOURNAL OF PHYSICAL CHEMISTRY A,106(41),9499-9501.
MLA Ren, L,et al."Reaction of CH with NO2 studied by time-resolved FTIR spectroscopy".JOURNAL OF PHYSICAL CHEMISTRY A 106.41(2002):9499-9501.
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