ICCAS OpenIR
Synthesis and characterization of novel nickel(II) complexes bearing N,P ligands and their catalytic activity in ethylene oligomerization
Sun, WH; Li, ZL; Hu, HM; Wu, B; Yang, HJ; Zhu, N; Leng, XB; Wang, HG
2002
Source PublicationNEW JOURNAL OF CHEMISTRY
ISSN1144-0546
Volume26Issue:10Pages:1474-1478
AbstractThe novel chloro(1-naphthyl) [8-(diphenylphosphino) quinoline] nickel(II) (1), chloro(1-naphthyl) [2-methyl-8( diphenylphosphino) quinoline] nickel(II) (2), and [2-methyl-8- (diphenylphosphino) quinoline] nickel(II) dichloride ( 3) complexes were synthesized in satisfactory yield and fully characterized. The structures of complexes 1 and 3 were determined by single crystal X-ray analysis, which indicated that complex 1 exists in a square planar configuration, while complex 3 is dimeric square pyramidal. In the presence of MAO cocatalyst, complexes 1 3 displayed good catalytic activities for ethylene oligomerization in toluene, up to 2.45 x 10(5) g ethylene ( mol Ni.h.atm)(-1) by complex 3.
DOI10.1039/b203738f
Indexed ByIC ; CCR ; SCI
Language英语
WOS IDWOS:000178139400037
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:95[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78572
Collection中国科学院化学研究所
Corresponding AuthorSun, WH
Affiliation1.Chinese Acad Sci, Inst Chem, State Key Lab Engn Plast, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
3.Nankai Univ, State Key Lab Funct Polymer, Tianjin 300071, Peoples R China
Recommended Citation
GB/T 7714
Sun, WH,Li, ZL,Hu, HM,et al. Synthesis and characterization of novel nickel(II) complexes bearing N,P ligands and their catalytic activity in ethylene oligomerization[J]. NEW JOURNAL OF CHEMISTRY,2002,26(10):1474-1478.
APA Sun, WH.,Li, ZL.,Hu, HM.,Wu, B.,Yang, HJ.,...&Wang, HG.(2002).Synthesis and characterization of novel nickel(II) complexes bearing N,P ligands and their catalytic activity in ethylene oligomerization.NEW JOURNAL OF CHEMISTRY,26(10),1474-1478.
MLA Sun, WH,et al."Synthesis and characterization of novel nickel(II) complexes bearing N,P ligands and their catalytic activity in ethylene oligomerization".NEW JOURNAL OF CHEMISTRY 26.10(2002):1474-1478.
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