ICCAS OpenIR
Synthesis and crystal structure of cyclopentylindene rare earth complex (C5H9C9H6)(3)SMCl-Li+ (THF)(4)
Cui, DM; Tang, T; Cheng, JH; Hu, NH; Chen, WQ; Huang, BT
2002-02-01
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
Volume23Issue:2Pages:188-190
AbstractRare earth complex (C5H9C9H6)(3)SmCl-Li+ (THF)(4)( I ) was synthesized by reacting anhydrous SmCl3 with two equivalents of C5H9C9H6Li. From mix-solvent of THF and hexane, red color single crystals were obtained. The crystal belongs to a cubic system, space group P2(1)3 with unit cell parameters a= b=c= 1. 754 0(2) nm, alpha=beta=gamma=90degrees, V=5. 396 4(11) nm(3), Z = 4. The ten-coordinated samarium atom is bonded to three cyclopentylindenyl rings and a chlorine atom to form the anionic part of the title complex, ring centroids and the chlorine atom form a tortured tetrahedron around samarium. In the cationic part, lithium atom coordinates to four oxygen atoms of THF molecules to form a normal tetrahedron. The Sm-C(within the same ring) distance varies from 0. 268 to 0. 299 nm.
KeywordCyclopentylindene Samarium Rare Earth Complex
Indexed BySCI
Language英语
WOS IDWOS:000174163300006
PublisherHIGHER EDUCATION PRESS
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78546
Collection中国科学院化学研究所
Corresponding AuthorTang, T
Affiliation1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Jilin Univ Technol, Dept Chem Engn, Changchun 130012, Peoples R China
Recommended Citation
GB/T 7714
Cui, DM,Tang, T,Cheng, JH,et al. Synthesis and crystal structure of cyclopentylindene rare earth complex (C5H9C9H6)(3)SMCl-Li+ (THF)(4)[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,23(2):188-190.
APA Cui, DM,Tang, T,Cheng, JH,Hu, NH,Chen, WQ,&Huang, BT.(2002).Synthesis and crystal structure of cyclopentylindene rare earth complex (C5H9C9H6)(3)SMCl-Li+ (THF)(4).CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,23(2),188-190.
MLA Cui, DM,et al."Synthesis and crystal structure of cyclopentylindene rare earth complex (C5H9C9H6)(3)SMCl-Li+ (THF)(4)".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 23.2(2002):188-190.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Cui, DM]'s Articles
[Tang, T]'s Articles
[Cheng, JH]'s Articles
Baidu academic
Similar articles in Baidu academic
[Cui, DM]'s Articles
[Tang, T]'s Articles
[Cheng, JH]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Cui, DM]'s Articles
[Tang, T]'s Articles
[Cheng, JH]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.