ICCAS OpenIR
Catalytic behaviors of silica-supported methylcellulose-L-phenyl alanine-platinum complexes in asymmetric hydrogenation of diacetone alcohol
Huang, K; Xue, L; Huang, MY; Jiang, YY
2002-03-01
Source PublicationPOLYMERS FOR ADVANCED TECHNOLOGIES
ISSN1042-7147
Volume13Issue:3-4Pages:165-168
AbstractA new chiral natural bio-polymer-metal complexe, silica-supported methylcellulose-L-phenyl alanine-platinum complex (SiO2-MC-L-Phe-Pt) has been prepared by a very simple method, and the Pt complex has been found to be able to catalyze the asymmetric hydrogenation of diacetone alcohol to give (R)-(-)-2-methyl-2,4-pentan-diol at room temperature and under atmospheric hydrogen pressure, The product and optical yields of 2-methyl-2,4-pentandiol amounted to 67.0 and 92.7%, respectively. The product and optical yields were remarkably affected by the Pt content in the complex, the kind of solvent and the reaction temperature. This catalyst was very stable and could be reused several times without any remarkable change in optical catalytic activity. Copyright (C) 2002 John Wiley Sons, Ltd.
KeywordAsymmetric Hydrogenation Diacetone Alcohol Silica-supported Methylcellulose-l-phenyl Alanine Platinum Complex
DOI10.1002/pat.168
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000174200300002
PublisherJOHN WILEY & SONS LTD
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78504
Collection中国科学院化学研究所
Corresponding AuthorHuang, K
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Huang, K,Xue, L,Huang, MY,et al. Catalytic behaviors of silica-supported methylcellulose-L-phenyl alanine-platinum complexes in asymmetric hydrogenation of diacetone alcohol[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2002,13(3-4):165-168.
APA Huang, K,Xue, L,Huang, MY,&Jiang, YY.(2002).Catalytic behaviors of silica-supported methylcellulose-L-phenyl alanine-platinum complexes in asymmetric hydrogenation of diacetone alcohol.POLYMERS FOR ADVANCED TECHNOLOGIES,13(3-4),165-168.
MLA Huang, K,et al."Catalytic behaviors of silica-supported methylcellulose-L-phenyl alanine-platinum complexes in asymmetric hydrogenation of diacetone alcohol".POLYMERS FOR ADVANCED TECHNOLOGIES 13.3-4(2002):165-168.
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