ICCAS OpenIR
Self-assembling directed synthesis of a novel terephthalamide-bridged ladderlike polysiloxane
Li, H; Liu, CQ; Guo, GQ; Zhou, XS; Zhang, JM; Shen, DY; Zhang, ZX; Xie, P; Yu, SY; Zhang, RB
2002-09-15
Source PublicationJOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
ISSN0887-624X
Volume40Issue:18Pages:3161-3170
AbstractA novel, soluble terephthalamide-bridged ladderlike polysiloxane (L) was synthesized successfully for the first time by stepwise coupling polymerization. The process involved the hydrogen-bonding self-assembly of amido groups, which resulted in the formation of a more highly ordered polymeric structure. A novel monomer, bis(3-methyldimetlioxysilylpropyl) terephthalamide (M), was prepared by a hydrosilylation reaction in the presence of dicyclopentadienyl platinum dichloride as a catalyst. The structures of the monomer (M) and the polymer (L) were characterized by Fourier transform infrared, H-1 NMR, C-13 NMR, Si-29 NMR, mass spectrometry, X-ray diffraction, differential scanning calorimetry, and vapor pressure osmometry. All the characterization data indicated that the synthesized polymer (L) possessed an ordered ladderlike structure. (C) 2002 Wiley Periodicals, Inc.
KeywordPolysiloxanes Self-assembly Templates
DOI10.1002/pola.10403
Indexed BySCI
Language英语
WOS IDWOS:000177633800008
PublisherWILEY-BLACKWELL
Citation statistics
Cited Times:19[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78478
Collection中国科学院化学研究所
Corresponding AuthorZhang, RB
Affiliation1.Acad Sinica, Polymer Chem Lab, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Polymer Phys & Chem,China Petrochem, Beijing 100080, Peoples R China
3.Acad Sinica, Grad Sch, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Li, H,Liu, CQ,Guo, GQ,et al. Self-assembling directed synthesis of a novel terephthalamide-bridged ladderlike polysiloxane[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2002,40(18):3161-3170.
APA Li, H.,Liu, CQ.,Guo, GQ.,Zhou, XS.,Zhang, JM.,...&Zhang, RB.(2002).Self-assembling directed synthesis of a novel terephthalamide-bridged ladderlike polysiloxane.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,40(18),3161-3170.
MLA Li, H,et al."Self-assembling directed synthesis of a novel terephthalamide-bridged ladderlike polysiloxane".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 40.18(2002):3161-3170.
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