ICCAS OpenIR
Synthesis of optically active beta-alkyl-alpha-methylene-gamma-butyrolactones from enantioselective biotransformation of nitriles, an unusual inversion of enantioselectivity
Zhao, SM; Wang, MX
2002-11-01
Source PublicationCHINESE JOURNAL OF CHEMISTRY
ISSN1001-604X
Volume20Issue:11Pages:1291-1299
AbstractA new approach to optically active beta-alltyl-alpha-methylene-gamma-bu-tyrolactone derivatives was reported from the Rhodococcus sp. AJ270-catalyzed hydrolysis of appropriate nitriles. The inversion of enantioselectivity of the amidase has been observed when a methyl protection was introduced into the hydroxy group of the parent substrate.
KeywordBiotransformation Nitrile Hydratase Amidase Optically Active Beta-alkyl-alpha-methylene-gamma-butyrolactone Inversion Of Enantioselectivity
Indexed BySCI ; IC ; CCR
Language英语
WOS IDWOS:000179210800024
PublisherSCIENCE CHINA PRESS
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78328
Collection中国科学院化学研究所
Corresponding AuthorWang, MX
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhao, SM,Wang, MX. Synthesis of optically active beta-alkyl-alpha-methylene-gamma-butyrolactones from enantioselective biotransformation of nitriles, an unusual inversion of enantioselectivity[J]. CHINESE JOURNAL OF CHEMISTRY,2002,20(11):1291-1299.
APA Zhao, SM,&Wang, MX.(2002).Synthesis of optically active beta-alkyl-alpha-methylene-gamma-butyrolactones from enantioselective biotransformation of nitriles, an unusual inversion of enantioselectivity.CHINESE JOURNAL OF CHEMISTRY,20(11),1291-1299.
MLA Zhao, SM,et al."Synthesis of optically active beta-alkyl-alpha-methylene-gamma-butyrolactones from enantioselective biotransformation of nitriles, an unusual inversion of enantioselectivity".CHINESE JOURNAL OF CHEMISTRY 20.11(2002):1291-1299.
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