ICCAS OpenIR
Polymer immobilized silane bridged metallocene catalysts for ethylene polymerization
Zhu, HB; Jin, GX; Hu, NH
2002-08-01
Source PublicationJOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN0022-328X
Volume655Issue:1-2Pages:167-171
AbstractAnsa-zirconocene complex with an allyl substituted silane bridge [(CH2=CHCH2)CH3Si(C5H4)(2)]ZrCl2 (1a) has been synthesized and characterized. The molecular structure of la has been determined by X-ray crystallographic analysis. The polymer immobilized metallocene catalyst 1b is prepared by the co-polymerization of la with styrene in the presence of radical initiator. The result of ethylene polymerization showed that the polymer immobilized metallocene catalyst kept high activity for ethylene polymerization and was a potential supported catalyst for olefin polymerization. (C) 2002 Published by Elsevier Science B.V.
KeywordMetallocene Catalysts Polymer Immobilized Metallocene Silane Bridged Metallocene Ethylene Polymerization X-ray Structure Analysis
Indexed ByIC ; CCR ; SCI
Language英语
WOS IDWOS:000176957500021
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:31[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78318
Collection中国科学院化学研究所
Corresponding AuthorJin, GX
Affiliation1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
Recommended Citation
GB/T 7714
Zhu, HB,Jin, GX,Hu, NH. Polymer immobilized silane bridged metallocene catalysts for ethylene polymerization[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2002,655(1-2):167-171.
APA Zhu, HB,Jin, GX,&Hu, NH.(2002).Polymer immobilized silane bridged metallocene catalysts for ethylene polymerization.JOURNAL OF ORGANOMETALLIC CHEMISTRY,655(1-2),167-171.
MLA Zhu, HB,et al."Polymer immobilized silane bridged metallocene catalysts for ethylene polymerization".JOURNAL OF ORGANOMETALLIC CHEMISTRY 655.1-2(2002):167-171.
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