ICCAS OpenIR
Wacker oxidation of 1-hexene in 1-n-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]), supercritical (SC) CO2, and SCCO2/[bmim][PF6] mixed solvent
Hou, ZS; Han, BX; Gao, L; Jiang, T; Liu, ZM; Chang, YH; Zhang, XG; He, J
2002
Source PublicationNEW JOURNAL OF CHEMISTRY
ISSN1144-0546
Volume26Issue:9Pages:1246-1248
AbstractOxidation of 1-hexene by molecular oxygen is conducted in 1-n-butyl-3-methylimidazolium hexafluorophosphate [bmim] [PF6], supercritical (SC) CO2, SCCO2 / [bmim] [PF6] mixed solvent, and in the absence of solvent. The selectivity to the desired product 2-hexanone is much higher when the reaction is carried out in the mixed solvent, and the catalysts is more stable in SC CO2/[bmim] [PF6] mixed solvent than in SC CO2.
DOI10.1039/b201997c
Indexed ByCCR ; SCI
Language英语
WOS IDWOS:000177603300026
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78200
Collection中国科学院化学研究所
Corresponding AuthorHan, BX
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Hou, ZS,Han, BX,Gao, L,et al. Wacker oxidation of 1-hexene in 1-n-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]), supercritical (SC) CO2, and SCCO2/[bmim][PF6] mixed solvent[J]. NEW JOURNAL OF CHEMISTRY,2002,26(9):1246-1248.
APA Hou, ZS.,Han, BX.,Gao, L.,Jiang, T.,Liu, ZM.,...&He, J.(2002).Wacker oxidation of 1-hexene in 1-n-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]), supercritical (SC) CO2, and SCCO2/[bmim][PF6] mixed solvent.NEW JOURNAL OF CHEMISTRY,26(9),1246-1248.
MLA Hou, ZS,et al."Wacker oxidation of 1-hexene in 1-n-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]), supercritical (SC) CO2, and SCCO2/[bmim][PF6] mixed solvent".NEW JOURNAL OF CHEMISTRY 26.9(2002):1246-1248.
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