ICCAS OpenIR
Mass spectrometric study of Ag/Se cluster ions and reaction of Ag and Se clusters
Xing, XP; Zhao, X; Zhang, X; Gao, Z
2002-03-01
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN0251-0790
Volume23Issue:3Pages:428-431
AbstractThe time-of-flight mass spectrometry was used to study Ag/Se cluster ions produced by laser ablation of solid samples, and a Laser Double Ablation Reactor was used to study the reaction of Ag and Se clusters. In Ag/Se binary cluster ions produced by laser ablation, [(Ag2Se)(n)Ag+], [(Ag2Se)(n)Ag-3(+)] are main compositions of positive cluster ions, while [(Ag2Se)(n)AgSe-], [(Ag2Se)(n)AgSe2-], [(Ag2Se)(n)Se-] are main compositions of negative cluster ions. The photolysis rates of positive cluster ions is higher than those of Ag/S clusters. During the laser double ablation experiment, the AgSen+ (n=4-9), AgSen- (n=4-7) were detected. In the series AgSe4+, the ions AgSe4+, AgSe6+ are comparatively abundant. It seems that the clustering mechanisms in the two processes are different.
KeywordLaser Ablation Time-of-flight Mass Spectrometer Clusters Reaction Ag/se Atom Clusters
Indexed BySCI
Language英语
WOS IDWOS:000175465700024
PublisherHIGHER EDUCATION PRESS
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78196
Collection中国科学院化学研究所
Corresponding AuthorGao, Z
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Xing, XP,Zhao, X,Zhang, X,et al. Mass spectrometric study of Ag/Se cluster ions and reaction of Ag and Se clusters[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,23(3):428-431.
APA Xing, XP,Zhao, X,Zhang, X,&Gao, Z.(2002).Mass spectrometric study of Ag/Se cluster ions and reaction of Ag and Se clusters.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,23(3),428-431.
MLA Xing, XP,et al."Mass spectrometric study of Ag/Se cluster ions and reaction of Ag and Se clusters".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 23.3(2002):428-431.
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