ICCAS OpenIR
Synthesis and self-assembly of 2,9,16-tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine and the application of its self-assembled monolayers in organic light-emitting diodes
Huang, XB; Liu, YQ; Wang, S; Zhou, SQ; Zhu, DB
2002-09-16
Source PublicationCHEMISTRY-A EUROPEAN JOURNAL
ISSN0947-6539
Volume8Issue:18Pages:4179-4184
Abstract2,9,16-Tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine (8) and its disulfide (9) have been synthesized and characterized, and their self-assembling behaviors on gold substrates have been studied. Characteristic Q-bands were observed at about 630 nm in the UV/visible spectra of the self-assembling monolayers (SAMs). They were broadened and blue-shifted relative to those observed in solution. Binding energies for S2p have the same values (161.70 eV) and are in accord with those for gold thiolates. The application of the SAMs in organic light-emitting diode was investigated. It shows that the SAM promotes the hole injection process from the anode.
KeywordHole Injection Organic Light-emitting Diode Phthalocyanines Self-assembly Synthesis Design
Indexed ByIC ; SCI
Language英语
WOS IDWOS:000178146500009
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78184
Collection中国科学院化学研究所
Corresponding AuthorLiu, YQ
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Huang, XB,Liu, YQ,Wang, S,et al. Synthesis and self-assembly of 2,9,16-tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine and the application of its self-assembled monolayers in organic light-emitting diodes[J]. CHEMISTRY-A EUROPEAN JOURNAL,2002,8(18):4179-4184.
APA Huang, XB,Liu, YQ,Wang, S,Zhou, SQ,&Zhu, DB.(2002).Synthesis and self-assembly of 2,9,16-tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine and the application of its self-assembled monolayers in organic light-emitting diodes.CHEMISTRY-A EUROPEAN JOURNAL,8(18),4179-4184.
MLA Huang, XB,et al."Synthesis and self-assembly of 2,9,16-tri(tert-butyl)-23-(10-mercaptodecyloxy)phthalocyanine and the application of its self-assembled monolayers in organic light-emitting diodes".CHEMISTRY-A EUROPEAN JOURNAL 8.18(2002):4179-4184.
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