ICCAS OpenIR
Reaction of vinyl radical with O-2 studied by time-resolved infrared emission spectroscopy
Feng, WH; Wang, BS
2002-04-26
Source PublicationCHEMICAL PHYSICS LETTERS
ISSN0009-2614
Volume356Issue:5-6Pages:505-510
AbstractNascent products Of C2H3 + O-2 reaction have been studied by time-resolved FTIR emission spectroscopy. Vibrational excitation of reaction products H2CO, HCO, CO, and CO2 was observed, providing the evidence of existing two exothermic reaction channels: HCO + H2CO and CH3 + CO2 for the reaction. The latter channel was firstly observed in the experiment. Simulation of the spectrum of the products reveals that the highest excitation of CO and CO2(nu(3)) at 5 mus is nu = 4 and 6, respectively; the branching ratio of the channel HCO + H2CO to the channel CH3 + CO2 is estimated to be 17. (C) 2002 Published by Elsevier Science B.V.
Indexed BySCI
Language英语
WOS IDWOS:000175379000012
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78132
Collection中国科学院化学研究所
Corresponding AuthorFeng, WH
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Feng, WH,Wang, BS. Reaction of vinyl radical with O-2 studied by time-resolved infrared emission spectroscopy[J]. CHEMICAL PHYSICS LETTERS,2002,356(5-6):505-510.
APA Feng, WH,&Wang, BS.(2002).Reaction of vinyl radical with O-2 studied by time-resolved infrared emission spectroscopy.CHEMICAL PHYSICS LETTERS,356(5-6),505-510.
MLA Feng, WH,et al."Reaction of vinyl radical with O-2 studied by time-resolved infrared emission spectroscopy".CHEMICAL PHYSICS LETTERS 356.5-6(2002):505-510.
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