ICCAS OpenIR
Reactions of lead cluster ions with ethylene, propene, trans-butene, and cis-butene
Tian, ZX; Xing, XP; Tang, ZC
2002
Source PublicationRAPID COMMUNICATIONS IN MASS SPECTROMETRY
ISSN0951-4198
Volume16Issue:16Pages:1515-1520
AbstractReactions of lead cluster cations and anions with ethylene, propene, and trans-and cis-butene have been studied using a home-built reflectron time-of-flight mass spectrometer. Both the high- and low-energy pathway reactions were observed in the lead cluster reactions. For ethylene, only association products [Pb-k(C2H4)(n)(+)] were observed. For propene, both association products [Pb-k(C3H6)(n)(+)], high-energy energy pathway products [Pb-k(CH3)(+)] and their further association products [Pb-k(CH3)(m)(C3H6)(n)(+)] were observed, while for butenes, besides the three kinds of products mentioned above, Pb-k(C4H8)(n)(+),PbkCH3+ and Pb-k(CH3)(m)(C4H8)(n)(+), low-energy pathway products [PbkC4H6+,PbkC3H3(5)+, PbkC3H2(3)+ (for cis-butene only)] and their further association products [PbkC4H6(C4H8)(n)(+), PbkC3H3(5)(C4H8)(n)(+),PbkC3H2(3)(C4H8)(n)(+) (for cis-butene only)] were also observed. Bond selectivity and effects of steric hindrance were observed in the low-energy pathway reactions of lead cluster cations with trans- and cis-butene. The same anionic products, PbkCm-, with nearly the same intensity distribution, were observed in the reactions of lead cluster anions with all four alkenes studied here. Some reaction mechanisms are proposed for these reactions. Copyright (C) 2002 John Wiley Sons, Ltd.
DOI10.1002/rcm.745
Indexed BySCI
Language英语
WOS IDWOS:000177485900002
PublisherJOHN WILEY & SONS LTD
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78104
Collection中国科学院化学研究所
Corresponding AuthorTang, ZC
AffiliationAcad Sinica, Inst Chem, State Key Lab Mol React Dynam, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Tian, ZX,Xing, XP,Tang, ZC. Reactions of lead cluster ions with ethylene, propene, trans-butene, and cis-butene[J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY,2002,16(16):1515-1520.
APA Tian, ZX,Xing, XP,&Tang, ZC.(2002).Reactions of lead cluster ions with ethylene, propene, trans-butene, and cis-butene.RAPID COMMUNICATIONS IN MASS SPECTROMETRY,16(16),1515-1520.
MLA Tian, ZX,et al."Reactions of lead cluster ions with ethylene, propene, trans-butene, and cis-butene".RAPID COMMUNICATIONS IN MASS SPECTROMETRY 16.16(2002):1515-1520.
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