ICCAS OpenIR
Preparation of silica-supported methylcellulose-L-proline-Pt complex and its catalytic behaviors in asymmetric hydrogenation of propiophenone
Huang, K; Xue, L; Huang, MY; Jiang, YY
2001-11-01
Source PublicationPOLYMERS FOR ADVANCED TECHNOLOGIES
ISSN1042-7147
Volume12Issue:11-12Pages:647-650
AbstractA new chiral polymer-metal complex, silica-supported methylcellulose-L-proline-Pt complex (SiO2-MC-LP-Pt) has been found to be a high optically active catalyst for asymmetric hydrogenation of propiophenone to (R)-1-phenyl-1-propanol at 30degreesC and under atmospheric hydrogen pressure. The product and optical yields of 1-phenyl-1-propanol amounted to 62.5 and 92.2%, respectively. The product and optical yields were remarkably affected by the Pt content in the complex, the kind of solvent and the reaction temperature. This catalyst was very stable and could be reused several times without remarkable change in optical catalytic activity. Copyright (C) 2001 John Wiley Sons, Ltd.
KeywordMethylcellulose-l-proline-pt Complex Asymmetric Hydrogenation Optical Selectivity Propiophenone
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000173124400007
PublisherJOHN WILEY & SONS LTD
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/78080
Collection中国科学院化学研究所
Corresponding AuthorHuang, K
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Huang, K,Xue, L,Huang, MY,et al. Preparation of silica-supported methylcellulose-L-proline-Pt complex and its catalytic behaviors in asymmetric hydrogenation of propiophenone[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2001,12(11-12):647-650.
APA Huang, K,Xue, L,Huang, MY,&Jiang, YY.(2001).Preparation of silica-supported methylcellulose-L-proline-Pt complex and its catalytic behaviors in asymmetric hydrogenation of propiophenone.POLYMERS FOR ADVANCED TECHNOLOGIES,12(11-12),647-650.
MLA Huang, K,et al."Preparation of silica-supported methylcellulose-L-proline-Pt complex and its catalytic behaviors in asymmetric hydrogenation of propiophenone".POLYMERS FOR ADVANCED TECHNOLOGIES 12.11-12(2001):647-650.
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