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| Studies on properties of tetra-p-nitro-tetra-O-alkyl-calix[4]arenes | |
| Lu, GY; Song, W; Liu, MH; Liu, F; Jin, CM | |
| 2001-06-01 | |
| Source Publication | CHINESE JOURNAL OF CHEMISTRY
 |
| ISSN | 1001-604X |
| Volume | 19Issue:6Pages:612-615 |
| Abstract | This paper reports the properties of the novel tetra-p-nitro-tetra-O-alkyl-calix[4]arenes (alkyl = n-C4H9, 1; n-C8H17 2; n-C12H25, 3; n-C16H33, 4), X-ray crystallographic analysis and H-1 NMR revealed that they exist as pinched cone conformation in crystal or cone conformation in solution. EFISH experiments at 1064 nm in CHCl3 indicated that tetra-p-nitro-tetra-O-butyl-calix[4]arene (1) has higher hyperpolarizability beta (z) values than the corresponding reference compound p-nitro-phenyl butyl ether, without red shift of the charge transfer band. Compounds 2, 3 and 4 with longer alkyl chains can form monolayer at the air/water. |
| Keyword | Calix[4]Arene Conformation Monolayer Nlo Property Crystal Structure |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000169449100012 |
| Publisher | SCIENCE PRESS |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.iccas.ac.cn/handle/121111/78070 |
| Collection | 中国科学院化学研究所 |
| Corresponding Author | Lu, GY |
| Affiliation | 1.Nanjing Univ, Dept Chem, Nanjing 210093, Jiangsu, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Colloid & Interface Sci, Beijing 100101, Peoples R China |
| Recommended Citation GB/T 7714 | Lu, GY,Song, W,Liu, MH,et al. Studies on properties of tetra-p-nitro-tetra-O-alkyl-calix[4]arenes[J]. CHINESE JOURNAL OF CHEMISTRY,2001,19(6):612-615. |
| APA | Lu, GY,Song, W,Liu, MH,Liu, F,&Jin, CM.(2001).Studies on properties of tetra-p-nitro-tetra-O-alkyl-calix[4]arenes.CHINESE JOURNAL OF CHEMISTRY,19(6),612-615. |
| MLA | Lu, GY,et al."Studies on properties of tetra-p-nitro-tetra-O-alkyl-calix[4]arenes".CHINESE JOURNAL OF CHEMISTRY 19.6(2001):612-615. |
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