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Synthesis and characterization of novel reactive polyorganosiloxane containing nitro groups | |
Liu, CQ; Liu, Y; Xie, P; Zhang, RB; He, CB; Chung, NTS | |
2001 | |
Source Publication | CHINESE JOURNAL OF POLYMER SCIENCE
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ISSN | 0256-7679 |
Volume | 19Issue:1Pages:1-6 |
Abstract | A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymerization. The monomer, 3-(4-nitrophenoxy)propylmethyldichlorosilane (NPPMS), was synthesized by hydrosilylation reaction with dicyciopentadienylplatinum(II) chloride (Cp2PtCl2) catalyst in high yield. The synthesized polynitroorganosiloxane, which has potential application as a precursor for synthesizing advanced functional polymers, was characterized by FTIR, H-1-NMR, C-13-NMR, Si-29-NMR, vapor pressure osmometry (VPO) and gel permeation chromatography(GPC). |
Keyword | Polyorganosiloxane Equilibration Polymerization Hydrosilylation Characterization |
Indexed By | SCI |
Language | 英语 |
WOS ID | WOS:000166329700001 |
Publisher | SPRINGER-VERLAG BERLIN |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.iccas.ac.cn/handle/121111/77998 |
Collection | 中国科学院化学研究所 |
Corresponding Author | Zhang, RB |
Affiliation | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, PCLCC, Beijing 100080, Peoples R China 2.Natl Univ Singapore, Inst Mat Res & Engn, Singapore 119260, Singapore |
Recommended Citation GB/T 7714 | Liu, CQ,Liu, Y,Xie, P,et al. Synthesis and characterization of novel reactive polyorganosiloxane containing nitro groups[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2001,19(1):1-6. |
APA | Liu, CQ,Liu, Y,Xie, P,Zhang, RB,He, CB,&Chung, NTS.(2001).Synthesis and characterization of novel reactive polyorganosiloxane containing nitro groups.CHINESE JOURNAL OF POLYMER SCIENCE,19(1),1-6. |
MLA | Liu, CQ,et al."Synthesis and characterization of novel reactive polyorganosiloxane containing nitro groups".CHINESE JOURNAL OF POLYMER SCIENCE 19.1(2001):1-6. |
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