ICCAS OpenIR
Role of boron species in the hydrogenation of o-chloronitrobenzene over polymer-stabilized ruthenium colloidal catalysts
Yan, XP; Liu, MH; Liu, HF; Liew, KY
2001-03-28
Source PublicationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN1381-1169
Volume169Issue:1-2Pages:225-233
AbstractThe role of boron species in selective hydrogenation of o-chloronitrobenzene (o-CNB) over polymer-stabilized ruthenium colloids has been studied. Of the two kinds of boron species (boride and berate) present in ruthenium colloids prepared by NaSH4 reduction, it was verified that only berate had a significant effect on the hydrogenation of o-CNB, while boride performed as a spectator. When metal cations were added into ruthenium colloidal catalyst system as modifiers, respectively, we observed that the synergetic effect between berate and metal cations occurred in these systems. It is suggested that metal complex ions were formed between the metal cations and berate ions. (C) 2001 Elsevier Science B.V. All rights reserved.
KeywordHydrogenation Ruthenium Colloid O-chloronitrobenzene Boron Species
Indexed BySCI
Language英语
WOS IDWOS:000167803100027
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:31[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77968
Collection中国科学院化学研究所
Corresponding AuthorLiu, HF
Affiliation1.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Polymer Chem Lab,PCLCC, Beijing 100080, Peoples R China
2.China Petro Chem Corp, Beijing 100080, Peoples R China
3.Univ Sains Malaysia, Sch Chem Sci, Minden 11800, Penang, Malaysia
Recommended Citation
GB/T 7714
Yan, XP,Liu, MH,Liu, HF,et al. Role of boron species in the hydrogenation of o-chloronitrobenzene over polymer-stabilized ruthenium colloidal catalysts[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2001,169(1-2):225-233.
APA Yan, XP,Liu, MH,Liu, HF,&Liew, KY.(2001).Role of boron species in the hydrogenation of o-chloronitrobenzene over polymer-stabilized ruthenium colloidal catalysts.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,169(1-2),225-233.
MLA Yan, XP,et al."Role of boron species in the hydrogenation of o-chloronitrobenzene over polymer-stabilized ruthenium colloidal catalysts".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 169.1-2(2001):225-233.
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