ICCAS OpenIR
Influence of temperature on lattice spacings of melt-crystallized poly(iminosebacoyl iminodecamethylene)
Yang, XN; Kong, XH; Tan, SS; Li, G; Zhou, E
2001-07-01
Source PublicationPOLYMER INTERNATIONAL
ISSN0959-8103
Volume50Issue:7Pages:817-821
AbstractThe variation of lattice spacings of poly(iminosebacoyl iminodecamethylene) (nylon-10,10) with temperature was studied by wide-angle X-ray diffraction (WAXD) during both heating and cooling processes, which demonstrates a gradual and continuous transition with temperature. However, the crystal melts before the two peaks merge completely. Both WAXD and differential scanning calorimetry show that crystallization from molten sample results directly in the triclinic form. Additionally, this transition is thermodynamically reversible. Comparison of this transition with that of nylon-6,6, suggests that no hydrogen-bonded network is formed during or after the transition. We prefer to attribute this transition to asymmetrical thermal expansion in the nylon-10,10 crystals rather than to a true first-order phase transition. (C) 2001 Society of Chemical Industry.
KeywordPa1010 Brill Transition Crystal Structure Nylon-10 10
Indexed BySCI
Language英语
WOS IDWOS:000169636600012
PublisherJOHN WILEY & SONS LTD
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77966
Collection中国科学院化学研究所
Corresponding AuthorZhou, E
AffiliationChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Yang, XN,Kong, XH,Tan, SS,et al. Influence of temperature on lattice spacings of melt-crystallized poly(iminosebacoyl iminodecamethylene)[J]. POLYMER INTERNATIONAL,2001,50(7):817-821.
APA Yang, XN,Kong, XH,Tan, SS,Li, G,&Zhou, E.(2001).Influence of temperature on lattice spacings of melt-crystallized poly(iminosebacoyl iminodecamethylene).POLYMER INTERNATIONAL,50(7),817-821.
MLA Yang, XN,et al."Influence of temperature on lattice spacings of melt-crystallized poly(iminosebacoyl iminodecamethylene)".POLYMER INTERNATIONAL 50.7(2001):817-821.
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