ICCAS OpenIR
Synthesis and third-order optical nonlinearity of some salts comprising planar pomplex cation and anion
Yang, CL; Qin, JG; Zhao, J; Si, JH; Dong, FZ; Wang, YG; Ye, PX; Ye, C
2001-03-15
Source PublicationSYNTHETIC METALS
ISSN0379-6779
Volume120Issue:1-3Pages:789-790
AbstractThird-order optical nonlinearity of some new salts, which consist of planar complex cation [Cu(L)(2)](2+) (L=2,2 ' -bipyridine or phenanthroline) and planar complex anion [M(mnt)(2)](2-) (M = Ni, Co, Cu or Pd: mnt = maleonitriledithiolate). were studied by degenerate four-wave mixing (DFWM) technique. It was found that these compounds exhibit large non-resonant nonlinearity at 1064 nln (gamma (1111) in the order of 10(-31)-10(-30) esu). and that among the molecules of the same series. the molecule with metallic ion of larger atomic number possesses larger nonlinear hyperpolarizability gamma (1111). The results also indicate that the third-order optical nonlinearity of these salts mainly comes from the part of complex cation.
KeywordSynthesis Nonlinear Optical Methods
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000168887500054
PublisherELSEVIER SCIENCE SA
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77868
Collection中国科学院化学研究所
Corresponding AuthorQin, JG
Affiliation1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Yang, CL,Qin, JG,Zhao, J,et al. Synthesis and third-order optical nonlinearity of some salts comprising planar pomplex cation and anion[J]. SYNTHETIC METALS,2001,120(1-3):789-790.
APA Yang, CL.,Qin, JG.,Zhao, J.,Si, JH.,Dong, FZ.,...&Ye, C.(2001).Synthesis and third-order optical nonlinearity of some salts comprising planar pomplex cation and anion.SYNTHETIC METALS,120(1-3),789-790.
MLA Yang, CL,et al."Synthesis and third-order optical nonlinearity of some salts comprising planar pomplex cation and anion".SYNTHETIC METALS 120.1-3(2001):789-790.
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