ICCAS OpenIR
Analysis of oxidative degradation products of 2,4,6-trichlorophenol treated with air ions
Ma, HM; Wohlers, J; Meierhenrich, U; Bernecker, A; Suling, V; Thiemann, W
2001-07-15
Source PublicationANALYTICAL CHEMISTRY
ISSN0003-2700
Volume73Issue:14Pages:3506-3510
AbstractThe analysis of oxidative degradation products of 2,4,6-trichlorophenol (TCP) treated with air ions, which are generated by electric discharge, is reported. Due to the complex nature of the degradation products, a combination of different detection techniques was employed to characterize them. The oxidative degradation of TCP is usually dependent on the treating approaches, and in this system, a stepwise degradation, beginning with the formation of a major product 2,6-dichloro-1,4-benzenediol as web as other minor ones (e.g., 3,5-dichlorocatechol) via substitution, is first proposed through a detailed analysis of GC/MS, etc., though some chromogenic quinones can transiently be present. Furthermore, high dechlorination (53%) was observed for TCP after a 60-min treatment, indicating that air ions can serve as an efficient dechlorination means.
Indexed BySCI
Language英语
WOS IDWOS:000169880300041
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77854
Collection中国科学院化学研究所
Corresponding AuthorMa, HM
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
2.Univ Bremen, Dept Chem, D-28334 Bremen, Germany
Recommended Citation
GB/T 7714
Ma, HM,Wohlers, J,Meierhenrich, U,et al. Analysis of oxidative degradation products of 2,4,6-trichlorophenol treated with air ions[J]. ANALYTICAL CHEMISTRY,2001,73(14):3506-3510.
APA Ma, HM,Wohlers, J,Meierhenrich, U,Bernecker, A,Suling, V,&Thiemann, W.(2001).Analysis of oxidative degradation products of 2,4,6-trichlorophenol treated with air ions.ANALYTICAL CHEMISTRY,73(14),3506-3510.
MLA Ma, HM,et al."Analysis of oxidative degradation products of 2,4,6-trichlorophenol treated with air ions".ANALYTICAL CHEMISTRY 73.14(2001):3506-3510.
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