ICCAS OpenIR
Rearrangement of P-N to P-O bonds in mass spectra of N-diisopropyloxyphosphoryl amino acids/alcohols
Chen, J; Chen, Y; Jiang, Y; Fu, H; Xin, B; Zhao, YF
2001
Source PublicationRAPID COMMUNICATIONS IN MASS SPECTROMETRY
ISSN0951-4198
Volume15Issue:20Pages:1936-1940
AbstractThe cationized N-diisopropyloxyphosphoryl amino acids/alcohols were analyzed by electrospray ionization tandem mass spectrometry. A rearrangement reaction leading to the P-N to P-O bond migration was observed, and cationized phosphoric acid isopropyl ester (PAIE) was formed. The rearrangement did not depend on the chain length of the amino acids/alcohols. A possible rearrangement mechanism was proposed. It was shown that the phosphoryl group has a strong affinity to the hydroxyl group in the gas phase. Copyright (C) 2001 John Wiley & Sons, Ltd.
Indexed BySCI
Language英语
WOS IDWOS:000171688300007
PublisherJOHN WILEY & SONS LTD
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77814
Collection中国科学院化学研究所
Corresponding AuthorZhao, YF
Affiliation1.Tsing Hua Univ, Sch Life Sci & Engn, Dept Chem, Minist Educ,Lab Bioorgan Phosphorus Chem, Beijing 100084, Peoples R China
2.Acad Sinica, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Chen, J,Chen, Y,Jiang, Y,et al. Rearrangement of P-N to P-O bonds in mass spectra of N-diisopropyloxyphosphoryl amino acids/alcohols[J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY,2001,15(20):1936-1940.
APA Chen, J,Chen, Y,Jiang, Y,Fu, H,Xin, B,&Zhao, YF.(2001).Rearrangement of P-N to P-O bonds in mass spectra of N-diisopropyloxyphosphoryl amino acids/alcohols.RAPID COMMUNICATIONS IN MASS SPECTROMETRY,15(20),1936-1940.
MLA Chen, J,et al."Rearrangement of P-N to P-O bonds in mass spectra of N-diisopropyloxyphosphoryl amino acids/alcohols".RAPID COMMUNICATIONS IN MASS SPECTROMETRY 15.20(2001):1936-1940.
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