ICCAS OpenIR
Metal complex effect on the hydrogenation of o-chloronitrobenzene over polymer-stabilized colloidal ruthenium clusters
Yan, XP; Liu, MH; Liu, HF; Liew, KY; Zhao, N
2001-05-14
Source PublicationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN1381-1169
Volume170Issue:1-2Pages:203-208
AbstractEffect of metal complex on hydrogenation of o-chloronitrobenzene (o-CNB) over poly-vinylpyrrolidone stabilized ruthenium colloid (PVP-Ru) has been studied in methanol media under 320 K and 4.0 MPa. The addition of Zn(II) complexes of diamines to PVP-Ru catalyst system leads to significant increase in the activity of PVP-Ru, while the selectivity for o-chloroaniline (o-CAN) maintained similar to 100%. Especially, rate enhancement more than 30 times that over neat PVP-Ru has been achieved in the presence of Zn(trien)Cl-2. It was verified that the incorporation of Zn(II) complexes of multi-amines changed the reaction kinetics. (C) 2001 Elsevier Science B.V. All rights reserved.
KeywordMetal Complex Colloidal Ruthenium Clusters Hydrogenation O-chloronitrobenzene
Indexed BySCI
Language英语
WOS IDWOS:000168613100022
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:19[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77752
Collection中国科学院化学研究所
Corresponding AuthorLiu, HF
Affiliation1.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Polymer Chem Lab, Beijing 100080, Peoples R China
2.Univ Sains Malaysia, Sch Chem Sci, Pulau Pinang 11800, Malaysia
Recommended Citation
GB/T 7714
Yan, XP,Liu, MH,Liu, HF,et al. Metal complex effect on the hydrogenation of o-chloronitrobenzene over polymer-stabilized colloidal ruthenium clusters[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2001,170(1-2):203-208.
APA Yan, XP,Liu, MH,Liu, HF,Liew, KY,&Zhao, N.(2001).Metal complex effect on the hydrogenation of o-chloronitrobenzene over polymer-stabilized colloidal ruthenium clusters.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,170(1-2),203-208.
MLA Yan, XP,et al."Metal complex effect on the hydrogenation of o-chloronitrobenzene over polymer-stabilized colloidal ruthenium clusters".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 170.1-2(2001):203-208.
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