ICCAS OpenIR
Synthesis and asymmetric polymerization of a series of methyl-substituted triphenylmethyl methacrylate
Chen, CF; Yang, YH; Xi, F
2001-02-01
Source PublicationJOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
ISSN0887-624X
Volume39Issue:3Pages:430-436
AbstractFive novel ortho-, meta-, and para-methyl-substituted triphenylmethyl methacrylate monomers, such as o-tolyldiphenylmethyl methacrylate (o-MeTrMA), di-o-tolylphenylmethyl methacrylate (o-Me(2)TrMA), tris-o-tolylmethyl methacrylate (o-Me(3)TrMA), tris-m-tolylmethyl methacrylate (m-Me(3)TrMA), and tris-p-tolylmethyl methacrylate (p-Me(3)TrMA) have been synthesized. The methanolysis rates of these monomers were measured in CDCl3-CD3OD (1:1, v/v) by H-1 NMR spectroscopy at 30 degreesC. It was found that the order of the methanolysis rates would be TrMAo-Me(2)TrMA>o-Me(3)TrMA and m-Me(3)TrMA>p-Me(3)TrMA>o-Me(3)TrMA. These differences would be attributed to the different sizes and "propeller" steric structures of the bulky side groups. (C) 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 430-436, 2001.
KeywordPoly(Triphenylmethyl Methacrylate) Asymmetric Polymerization Methanolysis
Indexed BySCI
Language英语
WOS IDWOS:000166508900011
PublisherJOHN WILEY & SONS INC
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77720
Collection中国科学院化学研究所
Corresponding AuthorChen, CF
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Chen, CF,Yang, YH,Xi, F. Synthesis and asymmetric polymerization of a series of methyl-substituted triphenylmethyl methacrylate[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2001,39(3):430-436.
APA Chen, CF,Yang, YH,&Xi, F.(2001).Synthesis and asymmetric polymerization of a series of methyl-substituted triphenylmethyl methacrylate.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,39(3),430-436.
MLA Chen, CF,et al."Synthesis and asymmetric polymerization of a series of methyl-substituted triphenylmethyl methacrylate".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 39.3(2001):430-436.
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