ICCAS OpenIR
Reactions of first-row transition metal ions with propargyl alcohol in the gas phase
Zhao, X; Xin, B; Xing, XP; Zhang, X; Wang, GH; Gao, Z
2001
Source PublicationRAPID COMMUNICATIONS IN MASS SPECTROMETRY
ISSN0951-4198
Volume15Issue:15Pages:1317-1321
AbstractThe gas-phase reactions with propargyl alcohol (PPA) of all the singly charged ions of the first-row transition metals, generated by laser ablation in an external ion source, were studied by Fourier transform ion cyclotron resonance mass spectrometry (FT-ICRMS.). The reactivities of the metal ions change irregularly across the periodic table, and the reactivity of each ion is a function of its electronic configuration and corresponding metal-oxygen (M-O) bond energies. The 10 metal ions were classified into three categories according to their reactivities: Sc+, Ti+ and V+ are the most reactive ions which react with PPA to give many kinds of oxygen-rich products due to stronger M-O bonds; Fe+, Co+ and Ni+ are less reactive; Cr+, Mn+, Cu+ and Zn+ are the most unreactive ions, due to the half and completely occupied valence electronic configurations. The order of reactivity is Ti+ > V+ > Sc+ > Co+ > Fe+ approximate to Ni+ > Zn+ > Cr+ approximate to Mn+ approximate to Cu+. Copyright (C) 2001 John Wiley & Sons, Ltd.
Indexed BySCI
Language英语
WOS IDWOS:000170219300013
PublisherJOHN WILEY & SONS LTD
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/77710
Collection中国科学院化学研究所
Corresponding AuthorZhao, X
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Mass Spectrometry Ctr, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhao, X,Xin, B,Xing, XP,et al. Reactions of first-row transition metal ions with propargyl alcohol in the gas phase[J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY,2001,15(15):1317-1321.
APA Zhao, X,Xin, B,Xing, XP,Zhang, X,Wang, GH,&Gao, Z.(2001).Reactions of first-row transition metal ions with propargyl alcohol in the gas phase.RAPID COMMUNICATIONS IN MASS SPECTROMETRY,15(15),1317-1321.
MLA Zhao, X,et al."Reactions of first-row transition metal ions with propargyl alcohol in the gas phase".RAPID COMMUNICATIONS IN MASS SPECTROMETRY 15.15(2001):1317-1321.
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